A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybrids

In this study, a novel ratiometric fluorescent nanoprobe for pH monitoring has been developed by synthesizing red fluorescent Ag2S quantum dots (Ag2S QDs) and green fluorescent carbon dots (CDs) nanohybrids (Ag2S CDs) in one pot using CDs as templates. The nanoprobe exhibits dual-emission peaks at 5...

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Main Authors: Xiaoxue Lei, Yiying Fu, Yuan Wu, Lu Chen, Jiangong Liang
Format: Article
Language:English
Published: The Royal Society 2020-07-01
Series:Royal Society Open Science
Subjects:
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.200482
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author Xiaoxue Lei
Yiying Fu
Yuan Wu
Lu Chen
Jiangong Liang
author_facet Xiaoxue Lei
Yiying Fu
Yuan Wu
Lu Chen
Jiangong Liang
author_sort Xiaoxue Lei
collection DOAJ
description In this study, a novel ratiometric fluorescent nanoprobe for pH monitoring has been developed by synthesizing red fluorescent Ag2S quantum dots (Ag2S QDs) and green fluorescent carbon dots (CDs) nanohybrids (Ag2S CDs) in one pot using CDs as templates. The nanoprobe exhibits dual-emission peaks at 500 and 670 nm under a single-excitation wavelength of 450 nm. The red fluorescence can be selectively quenched by increasing pH, while the green fluorescence is an internal reference. Therefore, the change of the relative fluorescence intensity (I500/I670) in the ratiometric Ag2S CDs probes can be used for pH sensing. The results revealed that I500/I670 of Ag2S CDs probes was linearly related to pH variation between pH 5.4 and 6.8. Meanwhile, the Ag2S CDs probes possessed a good reversibility along with pH changing between 5.0 and 7.0 without any interruption from common metal ions, proteins and other interferences.
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spelling doaj.art-b7fb831fc2f6435da264c9406d0c18062022-12-21T23:39:37ZengThe Royal SocietyRoyal Society Open Science2054-57032020-07-017710.1098/rsos.200482200482A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybridsXiaoxue LeiYiying FuYuan WuLu ChenJiangong LiangIn this study, a novel ratiometric fluorescent nanoprobe for pH monitoring has been developed by synthesizing red fluorescent Ag2S quantum dots (Ag2S QDs) and green fluorescent carbon dots (CDs) nanohybrids (Ag2S CDs) in one pot using CDs as templates. The nanoprobe exhibits dual-emission peaks at 500 and 670 nm under a single-excitation wavelength of 450 nm. The red fluorescence can be selectively quenched by increasing pH, while the green fluorescence is an internal reference. Therefore, the change of the relative fluorescence intensity (I500/I670) in the ratiometric Ag2S CDs probes can be used for pH sensing. The results revealed that I500/I670 of Ag2S CDs probes was linearly related to pH variation between pH 5.4 and 6.8. Meanwhile, the Ag2S CDs probes possessed a good reversibility along with pH changing between 5.0 and 7.0 without any interruption from common metal ions, proteins and other interferences.https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.200482ag2s quantum dotscarbon dotsratiometric fluorescent probeph detection
spellingShingle Xiaoxue Lei
Yiying Fu
Yuan Wu
Lu Chen
Jiangong Liang
A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybrids
Royal Society Open Science
ag2s quantum dots
carbon dots
ratiometric fluorescent probe
ph detection
title A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybrids
title_full A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybrids
title_fullStr A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybrids
title_full_unstemmed A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybrids
title_short A ratiometric fluorescent probe for pH detection based on Ag2S quantum dots–carbon dots nanohybrids
title_sort ratiometric fluorescent probe for ph detection based on ag2s quantum dots carbon dots nanohybrids
topic ag2s quantum dots
carbon dots
ratiometric fluorescent probe
ph detection
url https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.200482
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