Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction Pairs

Tribological properties of five anti-wear additives for a steel-copper contact were investigated. It was found that the tribological performances are closely related to the molecular structure of additives. The protic ionic liquid anti-wear additive AW316 exhibits the best tribological performance w...

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Main Authors: Huaigang Su, Yunlong Chen, Rui Ma, Weimin Li, Gaiqing Zhao, Yanxing Qi, Wenjing Lou
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Lubricants
Subjects:
Online Access:https://www.mdpi.com/2075-4442/10/5/91
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author Huaigang Su
Yunlong Chen
Rui Ma
Weimin Li
Gaiqing Zhao
Yanxing Qi
Wenjing Lou
author_facet Huaigang Su
Yunlong Chen
Rui Ma
Weimin Li
Gaiqing Zhao
Yanxing Qi
Wenjing Lou
author_sort Huaigang Su
collection DOAJ
description Tribological properties of five anti-wear additives for a steel-copper contact were investigated. It was found that the tribological performances are closely related to the molecular structure of additives. The protic ionic liquid anti-wear additive AW316 exhibits the best tribological performance with the lowest mean friction coefficient of 0.082, and the smallest wear volume, which is more than one order of magnitude smaller than base oil. Transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) tests reveal that a 10–15 nm thickness uniform boundary lubrication film composed of oxides, phosphates, and cuprous oxide was formed on the copper disc, which was responsible for its outstanding tribological performances.
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spelling doaj.art-b832dbee138347059673befbc85ea3962023-11-23T11:51:30ZengMDPI AGLubricants2075-44422022-05-011059110.3390/lubricants10050091Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction PairsHuaigang Su0Yunlong Chen1Rui Ma2Weimin Li3Gaiqing Zhao4Yanxing Qi5Wenjing Lou6State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaState Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, ChinaTribological properties of five anti-wear additives for a steel-copper contact were investigated. It was found that the tribological performances are closely related to the molecular structure of additives. The protic ionic liquid anti-wear additive AW316 exhibits the best tribological performance with the lowest mean friction coefficient of 0.082, and the smallest wear volume, which is more than one order of magnitude smaller than base oil. Transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) tests reveal that a 10–15 nm thickness uniform boundary lubrication film composed of oxides, phosphates, and cuprous oxide was formed on the copper disc, which was responsible for its outstanding tribological performances.https://www.mdpi.com/2075-4442/10/5/91anti-wear additivesionic liquidtribologysteel-copper
spellingShingle Huaigang Su
Yunlong Chen
Rui Ma
Weimin Li
Gaiqing Zhao
Yanxing Qi
Wenjing Lou
Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction Pairs
Lubricants
anti-wear additives
ionic liquid
tribology
steel-copper
title Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction Pairs
title_full Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction Pairs
title_fullStr Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction Pairs
title_full_unstemmed Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction Pairs
title_short Influence of Additive Chemistry on the Tribological Behavior of Steel/Copper Friction Pairs
title_sort influence of additive chemistry on the tribological behavior of steel copper friction pairs
topic anti-wear additives
ionic liquid
tribology
steel-copper
url https://www.mdpi.com/2075-4442/10/5/91
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AT weiminli influenceofadditivechemistryonthetribologicalbehaviorofsteelcopperfrictionpairs
AT gaiqingzhao influenceofadditivechemistryonthetribologicalbehaviorofsteelcopperfrictionpairs
AT yanxingqi influenceofadditivechemistryonthetribologicalbehaviorofsteelcopperfrictionpairs
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