[μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene)
The title compound, [FeZr2(C5H5)4Cl2(C13H18B2)], is a heteronuclear complex that consists of a [3]ferrocenophane moiety substituted at each cyclopentadienyl (Cp) ring by a BH3 group; the BH3 group is bonded via two H atoms to the Zr atom of the zirconocene chloride moiety in a bidentate fashion. The...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-10-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813023933 |
| _version_ | 1818085554089099264 |
|---|---|
| author | Adelina Reichert Hans-Wolfram Lerner Matthias Wagner Michael Bolte |
| author_facet | Adelina Reichert Hans-Wolfram Lerner Matthias Wagner Michael Bolte |
| author_sort | Adelina Reichert |
| collection | DOAJ |
| description | The title compound, [FeZr2(C5H5)4Cl2(C13H18B2)], is a heteronuclear complex that consists of a [3]ferrocenophane moiety substituted at each cyclopentadienyl (Cp) ring by a BH3 group; the BH3 group is bonded via two H atoms to the Zr atom of the zirconocene chloride moiety in a bidentate fashion. The two Cp rings of the [3]ferrocenophane moiety are aligned at a dihedral angle of 8.9 (4)° arising from the strain of the propane-1,3-diyl bridge linking the two Cp rings. [One methylene group is disordered over two positions with a site-occupation factor of 0.552 (18) for the major occupied site.] The dihedral angles between the Cp rings at the two Zr atoms are 50.0 (3) and 51.7 (3)°. The bonding Zr...H distances are in the range 1.89 (7)–2.14 (7) Å. As the two Cp rings of the ferrocene unit are connected by an ansa bridge, the two Zr atoms approach each other at 6.485 (1) Å. The crystal packing features C—H...Cl interactions. |
| first_indexed | 2024-12-10T20:11:37Z |
| format | Article |
| id | doaj.art-b87ac3871ab04f5483150f3a81905a97 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:11:37Z |
| publishDate | 2013-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b87ac3871ab04f5483150f3a81905a972022-12-22T01:35:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-10-016910m534m53510.1107/S1600536813023933[μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene)Adelina ReichertHans-Wolfram LernerMatthias WagnerMichael BolteThe title compound, [FeZr2(C5H5)4Cl2(C13H18B2)], is a heteronuclear complex that consists of a [3]ferrocenophane moiety substituted at each cyclopentadienyl (Cp) ring by a BH3 group; the BH3 group is bonded via two H atoms to the Zr atom of the zirconocene chloride moiety in a bidentate fashion. The two Cp rings of the [3]ferrocenophane moiety are aligned at a dihedral angle of 8.9 (4)° arising from the strain of the propane-1,3-diyl bridge linking the two Cp rings. [One methylene group is disordered over two positions with a site-occupation factor of 0.552 (18) for the major occupied site.] The dihedral angles between the Cp rings at the two Zr atoms are 50.0 (3) and 51.7 (3)°. The bonding Zr...H distances are in the range 1.89 (7)–2.14 (7) Å. As the two Cp rings of the ferrocene unit are connected by an ansa bridge, the two Zr atoms approach each other at 6.485 (1) Å. The crystal packing features C—H...Cl interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536813023933 |
| spellingShingle | Adelina Reichert Hans-Wolfram Lerner Matthias Wagner Michael Bolte [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) Acta Crystallographica Section E |
| title | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
| title_full | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
| title_fullStr | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
| title_full_unstemmed | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
| title_short | [μ-3,3′-Bis(trihydroboryl)[3]ferrocenophane]bis(chloridozirconocene) |
| title_sort | 956 3 3 8242 bis trihydroboryl 3 ferrocenophane bis chloridozirconocene |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813023933 |
| work_keys_str_mv | AT adelinareichert 956338242bistrihydroboryl3ferrocenophanebischloridozirconocene AT hanswolframlerner 956338242bistrihydroboryl3ferrocenophanebischloridozirconocene AT matthiaswagner 956338242bistrihydroboryl3ferrocenophanebischloridozirconocene AT michaelbolte 956338242bistrihydroboryl3ferrocenophanebischloridozirconocene |