Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrate
The asymmetric unit of the title compound, 2C8H9N2+·2ClO4−·H2O, consists of two (4-cyanobenzyl)>ammonium cations, two disordered ClO4− anions and one water molecule. The differences in the two cations are reflected in the N&#82...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811048884 |
| _version_ | 1828137798038716416 |
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| author | Yao Huang |
| author_facet | Yao Huang |
| author_sort | Yao Huang |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, 2C8H9N2+·2ClO4−·H2O, consists of two (4-cyanobenzyl)>ammonium cations, two disordered ClO4− anions and one water molecule. The differences in the two cations are reflected in the N—C—C—C torsion angles [−94.7 (3) and −115.9 (3)°]. In addition, the cations show different hydrogen-bonding patterns as one N atom bonds to two O atoms of ClO4− ions, while the other N atom is involved in hydrogen bonding with the O atoms of the ClO4− ions and water molecules. In the crystal, N—H...O and O—H...O hydrogen bonds result in a three-dimensional network. An O atom in each of the anions is disordered over two positions of equal occupancy. |
| first_indexed | 2024-04-11T18:24:28Z |
| format | Article |
| id | doaj.art-b87d6d683a5345e6be624d731e91714e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:24:28Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b87d6d683a5345e6be624d731e91714e2022-12-22T04:09:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3431o343110.1107/S1600536811048884Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrateYao HuangThe asymmetric unit of the title compound, 2C8H9N2+·2ClO4−·H2O, consists of two (4-cyanobenzyl)>ammonium cations, two disordered ClO4− anions and one water molecule. The differences in the two cations are reflected in the N—C—C—C torsion angles [−94.7 (3) and −115.9 (3)°]. In addition, the cations show different hydrogen-bonding patterns as one N atom bonds to two O atoms of ClO4− ions, while the other N atom is involved in hydrogen bonding with the O atoms of the ClO4− ions and water molecules. In the crystal, N—H...O and O—H...O hydrogen bonds result in a three-dimensional network. An O atom in each of the anions is disordered over two positions of equal occupancy.http://scripts.iucr.org/cgi-bin/paper?S1600536811048884 |
| spellingShingle | Yao Huang Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrate Acta Crystallographica Section E |
| title | Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrate |
| title_full | Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrate |
| title_fullStr | Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrate |
| title_full_unstemmed | Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrate |
| title_short | Bis[(4-cyanobenzyl)ammonium] bis(perchlorate) monohydrate |
| title_sort | bis 4 cyanobenzyl ammonium bis perchlorate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811048884 |
| work_keys_str_mv | AT yaohuang bis4cyanobenzylammoniumbisperchloratemonohydrate |