A New Technology for Utilization of Biomass Hydrolysis Residual Humins for Acetic Acid Production

Humins are a major byproduct formed from acid-catalyzed biomass hydrolysis and are usually considered as a low-value material. In this work, humins were completely degraded by a two-step technology, involving alkaline-catalytic hydrothermal treatment followed by wet oxidation. Using this technology,...

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Bibliographic Details
Main Authors: Shimin Kang, Gang Zhang, Qifei Yang, Junling Tu, Xiaojuan Guo, Frank G. F. Qin, Yongjun Xu
Format: Article
Language:English
Published: North Carolina State University 2016-09-01
Series:BioResources
Subjects:
Online Access:http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_11_4_9496_Kang_Utilization_Biomass_Hydrolysis_Humins
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Summary:Humins are a major byproduct formed from acid-catalyzed biomass hydrolysis and are usually considered as a low-value material. In this work, humins were completely degraded by a two-step technology, involving alkaline-catalytic hydrothermal treatment followed by wet oxidation. Using this technology, humins were converted to value-added acetic acid for first time. The highest acetic acid yield of 25.6% on a carbon basis or 37.2% on a mass basis was obtained with a purity of 46.2% based on the organic carbon in the aqueous product. This high-efficiency recovery of acetic acid is a new method for the effective utilization of humins, which is an important finding for biorefineries.
ISSN:1930-2126
1930-2126