Asymmetry in three-site relaxation exchange NMR

<p>The asymmetry of peak integrals in 2D relaxation maps of exchange between three sites indicates circular flow between the relaxation sites. This disagrees with the detailed balance according to which the exchange between any pair of sites must be balanced in terms of thermodynamic equilibri...

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Bibliographic Details
Main Authors: B. Blümich, M. Parziale, M. Augustine
Format: Article
Language:English
Published: Copernicus Publications 2023-08-01
Series:Magnetic Resonance
Online Access:https://mr.copernicus.org/articles/4/217/2023/mr-4-217-2023.pdf