Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-ene
The absolute configuration of the title compound, C16H23BrCl2, has been deduced from the chemical pathway and fully confirmed by refinement of the Flack and Hooft parameters. The six-membered ring adopts a half-chair conformation, whereas the seven-membered ring is a twisted chair. The molecular pac...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813028183 |
| _version_ | 1818083129161678848 |
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| author | Abdoullah Bimoussa Aziz Auhmani My Youssef Ait Itto Jean-Claude Daran Abdelwahed Auhmani |
| author_facet | Abdoullah Bimoussa Aziz Auhmani My Youssef Ait Itto Jean-Claude Daran Abdelwahed Auhmani |
| author_sort | Abdoullah Bimoussa |
| collection | DOAJ |
| description | The absolute configuration of the title compound, C16H23BrCl2, has been deduced from the chemical pathway and fully confirmed by refinement of the Flack and Hooft parameters. The six-membered ring adopts a half-chair conformation, whereas the seven-membered ring is a twisted chair. The molecular packing within the crystal is stabilized only by van der Waals interactions. |
| first_indexed | 2024-12-10T19:33:05Z |
| format | Article |
| id | doaj.art-b89f14f0e3ba4350ac292cd56b9c45a2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:33:05Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-b89f14f0e3ba4350ac292cd56b9c45a22022-12-22T01:36:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911o1692o169310.1107/S1600536813028183Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-eneAbdoullah BimoussaAziz AuhmaniMy Youssef Ait IttoJean-Claude DaranAbdelwahed AuhmaniThe absolute configuration of the title compound, C16H23BrCl2, has been deduced from the chemical pathway and fully confirmed by refinement of the Flack and Hooft parameters. The six-membered ring adopts a half-chair conformation, whereas the seven-membered ring is a twisted chair. The molecular packing within the crystal is stabilized only by van der Waals interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536813028183 |
| spellingShingle | Abdoullah Bimoussa Aziz Auhmani My Youssef Ait Itto Jean-Claude Daran Abdelwahed Auhmani Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-ene Acta Crystallographica Section E |
| title | Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-ene |
| title_full | Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-ene |
| title_fullStr | Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-ene |
| title_full_unstemmed | Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-ene |
| title_short | Absolute configuration of (1S,3R,8R)-10-bromomethyl-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]dodec-9-ene |
| title_sort | absolute configuration of 1s 3r 8r 10 bromomethyl 2 2 dichloro 3 7 7 trimethyltricyclo 6 4 0 01 3 dodec 9 ene |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813028183 |
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