Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions

Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions

ABSTRACTCu(im)2-derived Cu@N–C(600) catalyst has been efficiently utilized for the preparation of N-tosyl(H)−2-substituted indoles through one-pot domino Sonogashira coupling-cyclization reactions between N-tosyl(acetyl)−2-iodo anilines and aryl acetylenes. The catalytic system was heterogeneous and...

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Bibliographic Details
Main Authors: Jianwei Xie, Zhuangzhuang Wang, Huifang Ma, Shaofeng Gong
Format: Article
Language:English
Published: Taylor & Francis Group 2024-12-01
Series:Green Chemistry Letters and Reviews
Subjects:
MOF-derived catalyst
Cu@N–C
Sonogashira coupling-cyclization
2-substituted indole
heterogeneous catalyst
Online Access:https://www.tandfonline.com/doi/10.1080/17518253.2023.2296939
Description
Summary:ABSTRACTCu(im)2-derived Cu@N–C(600) catalyst has been efficiently utilized for the preparation of N-tosyl(H)−2-substituted indoles through one-pot domino Sonogashira coupling-cyclization reactions between N-tosyl(acetyl)−2-iodo anilines and aryl acetylenes. The catalytic system was heterogeneous and showed excellent functional group compatibility and could be performed well, affording the corresponding coupling products in good to excellent yields.
ISSN:1751-8253
1751-7192

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