Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions

Cu(im)2-derived Cu@N–C(600) catalyst has been efficiently utilized for the preparation of N-tosyl(H)−2-substituted indoles through one-pot domino Sonogashira coupling-cyclization reactions between N-tosyl(acetyl)−2-iodo anilines and aryl acetylenes. The catalytic system was heterogeneous and showed...

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Main Authors: Jianwei Xie, Zhuangzhuang Wang, Huifang Ma, Shaofeng Gong
פורמט: Article
שפה:English
יצא לאור: Taylor & Francis Group 2024-12-01
סדרה:Green Chemistry Letters and Reviews
נושאים:
גישה מקוונת:https://www.tandfonline.com/doi/10.1080/17518253.2023.2296939
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author Jianwei Xie
Zhuangzhuang Wang
Huifang Ma
Shaofeng Gong
author_facet Jianwei Xie
Zhuangzhuang Wang
Huifang Ma
Shaofeng Gong
author_sort Jianwei Xie
collection DOAJ
description Cu(im)2-derived Cu@N–C(600) catalyst has been efficiently utilized for the preparation of N-tosyl(H)−2-substituted indoles through one-pot domino Sonogashira coupling-cyclization reactions between N-tosyl(acetyl)−2-iodo anilines and aryl acetylenes. The catalytic system was heterogeneous and showed excellent functional group compatibility and could be performed well, affording the corresponding coupling products in good to excellent yields.
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spelling doaj.art-b8c1261735cb44c288e5a280cdad85472024-12-06T01:41:30ZengTaylor & Francis GroupGreen Chemistry Letters and Reviews1751-82531751-71922024-12-0117110.1080/17518253.2023.2296939Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactionsJianwei Xie0Zhuangzhuang Wang1Huifang Ma2Shaofeng Gong3College of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou, People’s Republic of ChinaCollege of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou, People’s Republic of ChinaSchool of Medicine & Health Sciences, Guangzhou Huashang College, Guangzhou, People’s Republic of ChinaCollege of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou, People’s Republic of ChinaCu(im)2-derived Cu@N–C(600) catalyst has been efficiently utilized for the preparation of N-tosyl(H)−2-substituted indoles through one-pot domino Sonogashira coupling-cyclization reactions between N-tosyl(acetyl)−2-iodo anilines and aryl acetylenes. The catalytic system was heterogeneous and showed excellent functional group compatibility and could be performed well, affording the corresponding coupling products in good to excellent yields.https://www.tandfonline.com/doi/10.1080/17518253.2023.2296939MOF-derived catalystCu@N–CSonogashira coupling-cyclization2-substituted indoleheterogeneous catalyst
spellingShingle Jianwei Xie
Zhuangzhuang Wang
Huifang Ma
Shaofeng Gong
Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions
Green Chemistry Letters and Reviews
MOF-derived catalyst
Cu@N–C
Sonogashira coupling-cyclization
2-substituted indole
heterogeneous catalyst
title Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions
title_full Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions
title_fullStr Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions
title_full_unstemmed Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions
title_short Cu(im)2-derived Cu@N–C catalyst for one-pot synthesis of 2-substituted indoles via domino Sonogashira coupling-cyclization reactions
title_sort cu im 2 derived cu n c catalyst for one pot synthesis of 2 substituted indoles via domino sonogashira coupling cyclization reactions
topic MOF-derived catalyst
Cu@N–C
Sonogashira coupling-cyclization
2-substituted indole
heterogeneous catalyst
url https://www.tandfonline.com/doi/10.1080/17518253.2023.2296939
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AT zhuangzhuangwang cuim2derivedcunccatalystforonepotsynthesisof2substitutedindolesviadominosonogashiracouplingcyclizationreactions
AT huifangma cuim2derivedcunccatalystforonepotsynthesisof2substitutedindolesviadominosonogashiracouplingcyclizationreactions
AT shaofenggong cuim2derivedcunccatalystforonepotsynthesisof2substitutedindolesviadominosonogashiracouplingcyclizationreactions