Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and Performance

To achieve net-zero iron and steel production by 2050, many iron and steel producers are turning to direct reduced iron (DRI)—electric arc furnace (EAF) steel production as an opportunity to achieve significant CO<sub>2</sub> emissions reductions relative to current levels. However, addi...

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Main Authors: Nicole Bond, Robert Symonds, Robin Hughes
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/15/14/5219
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author Nicole Bond
Robert Symonds
Robin Hughes
author_facet Nicole Bond
Robert Symonds
Robin Hughes
author_sort Nicole Bond
collection DOAJ
description To achieve net-zero iron and steel production by 2050, many iron and steel producers are turning to direct reduced iron (DRI)—electric arc furnace (EAF) steel production as an opportunity to achieve significant CO<sub>2</sub> emissions reductions relative to current levels. However, additional innovations are required to close the gap between DRI and net-zero steel. Pressurized chemical looping-DRI (PCL-DRI) is a novel technology explored to meet this target, in which the reformer firebox and fired process gas heaters are replaced with PCL combustion units. Captured CO<sub>2</sub> is conditioned and compressed for pipeline transportation and storage/utilization. The performance of two different PCL-DRI configurations relative to traditional DRI processes was explored via process simulation: a Midrex-type process and an Energiron-type process. The PCL-DRI processes were shown to have equivalent or lesser total fuel consumption (8% reduction) compared to the base cases, and greater process water production (170–260% increase), with minimal or no loss in thermal efficiency. PCL-DRI is a strong competitor to alternative methods of reaching net-zero DRI due to lower energy penalties for carbon capture, no required changes to stream chemistry in or out of the EAF, and no requirement for hydrogen infrastructure.
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spelling doaj.art-b8d61de513284527a2dc2fb88bdbc9fc2023-12-01T22:07:29ZengMDPI AGEnergies1996-10732022-07-011514521910.3390/en15145219Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and PerformanceNicole Bond0Robert Symonds1Robin Hughes2Natural Resources Canada, CanmetENERGY-Ottawa, Ottawa, ON K1A 1M1, CanadaNatural Resources Canada, CanmetENERGY-Ottawa, Ottawa, ON K1A 1M1, CanadaNatural Resources Canada, CanmetENERGY-Ottawa, Ottawa, ON K1A 1M1, CanadaTo achieve net-zero iron and steel production by 2050, many iron and steel producers are turning to direct reduced iron (DRI)—electric arc furnace (EAF) steel production as an opportunity to achieve significant CO<sub>2</sub> emissions reductions relative to current levels. However, additional innovations are required to close the gap between DRI and net-zero steel. Pressurized chemical looping-DRI (PCL-DRI) is a novel technology explored to meet this target, in which the reformer firebox and fired process gas heaters are replaced with PCL combustion units. Captured CO<sub>2</sub> is conditioned and compressed for pipeline transportation and storage/utilization. The performance of two different PCL-DRI configurations relative to traditional DRI processes was explored via process simulation: a Midrex-type process and an Energiron-type process. The PCL-DRI processes were shown to have equivalent or lesser total fuel consumption (8% reduction) compared to the base cases, and greater process water production (170–260% increase), with minimal or no loss in thermal efficiency. PCL-DRI is a strong competitor to alternative methods of reaching net-zero DRI due to lower energy penalties for carbon capture, no required changes to stream chemistry in or out of the EAF, and no requirement for hydrogen infrastructure.https://www.mdpi.com/1996-1073/15/14/5219pressurized chemical looping combustionsyngas productioncarbon neutral ironmakingdirect reduced ironCO<sub>2</sub> capturedecarbonization
spellingShingle Nicole Bond
Robert Symonds
Robin Hughes
Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and Performance
Energies
pressurized chemical looping combustion
syngas production
carbon neutral ironmaking
direct reduced iron
CO<sub>2</sub> capture
decarbonization
title Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and Performance
title_full Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and Performance
title_fullStr Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and Performance
title_full_unstemmed Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and Performance
title_short Pressurized Chemical Looping for Direct Reduced Iron Production: Carbon Neutral Process Configuration and Performance
title_sort pressurized chemical looping for direct reduced iron production carbon neutral process configuration and performance
topic pressurized chemical looping combustion
syngas production
carbon neutral ironmaking
direct reduced iron
CO<sub>2</sub> capture
decarbonization
url https://www.mdpi.com/1996-1073/15/14/5219
work_keys_str_mv AT nicolebond pressurizedchemicalloopingfordirectreducedironproductioncarbonneutralprocessconfigurationandperformance
AT robertsymonds pressurizedchemicalloopingfordirectreducedironproductioncarbonneutralprocessconfigurationandperformance
AT robinhughes pressurizedchemicalloopingfordirectreducedironproductioncarbonneutralprocessconfigurationandperformance