Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural Parameters of the Catalysts in Ethylene Polymerization
Hypothesis: The porosity of silica-based chromium catalysts is one of the important issues in the petrochemical industry due to the high catalytic activity attracted by university and industrial researchers. One of the most important parameters that strengthens the structure of the hydro...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | fas |
| Published: |
Iran Polymer and Petrochemical Institute
2021-08-01
|
| Series: | علوم و تکنولوژی پلیمر |
| Subjects: | |
| Online Access: | http://jips.ippi.ac.ir/article_1821_428c71fef6e550c186666c46da606198.pdf |
| _version_ | 1818716363768725504 |
|---|---|
| author | Ebrahim Ahmadi Seyyed Reza Razavi Mohamadreza Marefat |
| author_facet | Ebrahim Ahmadi Seyyed Reza Razavi Mohamadreza Marefat |
| author_sort | Ebrahim Ahmadi |
| collection | DOAJ |
| description | Hypothesis: The porosity of silica-based chromium catalysts is one of the important issues in the petrochemical industry due to the high catalytic activity attracted by university and industrial researchers. One of the most important parameters that strengthens the structure of the hydrogel is the aging process that is considered in this study. By performing the aging operation on the primary silica hydrogel, the size of the initial particles increases and the surface area decreases. By doing the drying process, the pore volume of silica is reduced due to the capillary force. With changing the solvent from water to alcohols and ethyl acetate, the pore volume of the silica supported also increases. This is due to the reduction in surface tension between the silica wall and the water in the cavities.Methods: The formation of supported silica using sol-gel method and the parameters affecting it have been investigated. Also, in the drying step by azeotropic distillation method, five solvents such as water, 1-propanol, 2-propanol, 1-butanol and ethyl acetate were used. FTIR, SEM and BET analyses were used to identify silica supported.Finding: The effect of organic solvents on pore volume was investigated; so that all hydrogels were synthesized under the same conditions, while different solvents were used in the drying step by azeotropic distillation method. The use of different organic solvents did not show significant changes in the specific surface area of the supported silica but caused significant changes in the its pore volume. The results showed that the morphology of the silica support was improved by solvent replacement using organic solvents and the best morphology and crack-free structure of the ethyl acetate solvent were reported. The highest catalytic activity of 80 kgPE/gCr.h was obtained for slurry polymerization with silica support dried by ethyl acetate solvent. |
| first_indexed | 2024-12-17T19:18:04Z |
| format | Article |
| id | doaj.art-b8f0e6ba8973426b86f80617caa89675 |
| institution | Directory Open Access Journal |
| issn | 1016-3255 2008-0883 |
| language | fas |
| last_indexed | 2024-12-17T19:18:04Z |
| publishDate | 2021-08-01 |
| publisher | Iran Polymer and Petrochemical Institute |
| record_format | Article |
| series | علوم و تکنولوژی پلیمر |
| spelling | doaj.art-b8f0e6ba8973426b86f80617caa896752022-12-21T21:35:42ZfasIran Polymer and Petrochemical Instituteعلوم و تکنولوژی پلیمر1016-32552008-08832021-08-0134323324710.22063/jipst.2021.18211821Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural Parameters of the Catalysts in Ethylene PolymerizationEbrahim Ahmadi0Seyyed Reza Razavi1Mohamadreza Marefat2Department of Chemistry, University of Zanjan, P.O. Box 45195-313, Zanjan, IranDepartment of Chemistry, University of Zanjan, P.O. Box 45195-313, Zanjan, IranDepartment of Chemistry, University of Zanjan, P.O. Box 45195-313, Zanjan, IranHypothesis: The porosity of silica-based chromium catalysts is one of the important issues in the petrochemical industry due to the high catalytic activity attracted by university and industrial researchers. One of the most important parameters that strengthens the structure of the hydrogel is the aging process that is considered in this study. By performing the aging operation on the primary silica hydrogel, the size of the initial particles increases and the surface area decreases. By doing the drying process, the pore volume of silica is reduced due to the capillary force. With changing the solvent from water to alcohols and ethyl acetate, the pore volume of the silica supported also increases. This is due to the reduction in surface tension between the silica wall and the water in the cavities.Methods: The formation of supported silica using sol-gel method and the parameters affecting it have been investigated. Also, in the drying step by azeotropic distillation method, five solvents such as water, 1-propanol, 2-propanol, 1-butanol and ethyl acetate were used. FTIR, SEM and BET analyses were used to identify silica supported.Finding: The effect of organic solvents on pore volume was investigated; so that all hydrogels were synthesized under the same conditions, while different solvents were used in the drying step by azeotropic distillation method. The use of different organic solvents did not show significant changes in the specific surface area of the supported silica but caused significant changes in the its pore volume. The results showed that the morphology of the silica support was improved by solvent replacement using organic solvents and the best morphology and crack-free structure of the ethyl acetate solvent were reported. The highest catalytic activity of 80 kgPE/gCr.h was obtained for slurry polymerization with silica support dried by ethyl acetate solvent.http://jips.ippi.ac.ir/article_1821_428c71fef6e550c186666c46da606198.pdfethylene polymerizationsolvent exchangesilica supportcr/sio2 catalystsol-gel method |
| spellingShingle | Ebrahim Ahmadi Seyyed Reza Razavi Mohamadreza Marefat Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural Parameters of the Catalysts in Ethylene Polymerization علوم و تکنولوژی پلیمر ethylene polymerization solvent exchange silica support cr/sio2 catalyst sol-gel method |
| title | Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural
Parameters of the Catalysts in Ethylene Polymerization |
| title_full | Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural
Parameters of the Catalysts in Ethylene Polymerization |
| title_fullStr | Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural
Parameters of the Catalysts in Ethylene Polymerization |
| title_full_unstemmed | Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural
Parameters of the Catalysts in Ethylene Polymerization |
| title_short | Synthesis of Chromium-Based Catalysts and Study of Various Solvents on the Morphology and Structural
Parameters of the Catalysts in Ethylene Polymerization |
| title_sort | synthesis of chromium based catalysts and study of various solvents on the morphology and structural parameters of the catalysts in ethylene polymerization |
| topic | ethylene polymerization solvent exchange silica support cr/sio2 catalyst sol-gel method |
| url | http://jips.ippi.ac.ir/article_1821_428c71fef6e550c186666c46da606198.pdf |
| work_keys_str_mv | AT ebrahimahmadi synthesisofchromiumbasedcatalystsandstudyofvarioussolventsonthemorphologyandstructuralparametersofthecatalystsinethylenepolymerization AT seyyedrezarazavi synthesisofchromiumbasedcatalystsandstudyofvarioussolventsonthemorphologyandstructuralparametersofthecatalystsinethylenepolymerization AT mohamadrezamarefat synthesisofchromiumbasedcatalystsandstudyofvarioussolventsonthemorphologyandstructuralparametersofthecatalystsinethylenepolymerization |