Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction
New highly active electrocatalysts were obtained by depositing bimetallic Pt-Cu nanoparticles on the surface of an N-doped carbon support. The structural–morphological characteristics and electrochemical behavior of the catalysts were studied. Using current stress testing protocols, their resistance...
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MDPI AG
2022-04-01
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Online Access: | https://www.mdpi.com/2073-4344/12/4/414 |
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author | Anastasia Alekseenko Angelina Pavlets Elizaveta Moguchikh Mikhail Tolstunov Evgeny Gribov Sergey Belenov Vladimir Guterman |
author_facet | Anastasia Alekseenko Angelina Pavlets Elizaveta Moguchikh Mikhail Tolstunov Evgeny Gribov Sergey Belenov Vladimir Guterman |
author_sort | Anastasia Alekseenko |
collection | DOAJ |
description | New highly active electrocatalysts were obtained by depositing bimetallic Pt-Cu nanoparticles on the surface of an N-doped carbon support. The structural–morphological characteristics and electrochemical behavior of the catalysts were studied. Using current stress testing protocols, their resistance to degradation was assessed in comparison with that of a commercial Pt/C material. A combined approach to catalyst synthesis that consists in alloying platinum with copper and doping the support makes it possible to obtain catalysts with a uniform distribution of bimetallic nanoparticles on the carbon surface. The obtained catalysts exhibit high activity and durability. |
first_indexed | 2024-03-09T11:02:29Z |
format | Article |
id | doaj.art-b901d957ce674414bdcae9c5f3a85b02 |
institution | Directory Open Access Journal |
issn | 2073-4344 |
language | English |
last_indexed | 2024-03-09T11:02:29Z |
publishDate | 2022-04-01 |
publisher | MDPI AG |
record_format | Article |
series | Catalysts |
spelling | doaj.art-b901d957ce674414bdcae9c5f3a85b022023-12-01T01:11:32ZengMDPI AGCatalysts2073-43442022-04-0112441410.3390/catal12040414Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction ReactionAnastasia Alekseenko0Angelina Pavlets1Elizaveta Moguchikh2Mikhail Tolstunov3Evgeny Gribov4Sergey Belenov5Vladimir Guterman6Faculty of Chemistry, Southern Federal University, 7 Zorge St, 344090 Rostov-on-Don, RussiaFaculty of Chemistry, Southern Federal University, 7 Zorge St, 344090 Rostov-on-Don, RussiaFaculty of Chemistry, Southern Federal University, 7 Zorge St, 344090 Rostov-on-Don, RussiaFaculty of Chemistry, Southern Federal University, 7 Zorge St, 344090 Rostov-on-Don, RussiaBoreskov Institute of Catalysis SB RAS, 5 Lavrentiev Ave., 630090 Novosibirsk, RussiaFaculty of Chemistry, Southern Federal University, 7 Zorge St, 344090 Rostov-on-Don, RussiaFaculty of Chemistry, Southern Federal University, 7 Zorge St, 344090 Rostov-on-Don, RussiaNew highly active electrocatalysts were obtained by depositing bimetallic Pt-Cu nanoparticles on the surface of an N-doped carbon support. The structural–morphological characteristics and electrochemical behavior of the catalysts were studied. Using current stress testing protocols, their resistance to degradation was assessed in comparison with that of a commercial Pt/C material. A combined approach to catalyst synthesis that consists in alloying platinum with copper and doping the support makes it possible to obtain catalysts with a uniform distribution of bimetallic nanoparticles on the carbon surface. The obtained catalysts exhibit high activity and durability.https://www.mdpi.com/2073-4344/12/4/414nanoparticlesPt electrocatalystsN-doped carbon supportbimetallic nanoparticlesoxygen reduction reactionstress testing |
spellingShingle | Anastasia Alekseenko Angelina Pavlets Elizaveta Moguchikh Mikhail Tolstunov Evgeny Gribov Sergey Belenov Vladimir Guterman Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction Catalysts nanoparticles Pt electrocatalysts N-doped carbon support bimetallic nanoparticles oxygen reduction reaction stress testing |
title | Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction |
title_full | Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction |
title_fullStr | Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction |
title_full_unstemmed | Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction |
title_short | Platinum-Containing Nanoparticles on N-Doped Carbon Supports as an Advanced Electrocatalyst for the Oxygen Reduction Reaction |
title_sort | platinum containing nanoparticles on n doped carbon supports as an advanced electrocatalyst for the oxygen reduction reaction |
topic | nanoparticles Pt electrocatalysts N-doped carbon support bimetallic nanoparticles oxygen reduction reaction stress testing |
url | https://www.mdpi.com/2073-4344/12/4/414 |
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