Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants
A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2017-05-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/22/5/835 |
| _version_ | 1828416741499207680 |
|---|---|
| author | Ruizhi Guo Lihao Liao Xiaodan Zhao |
| author_facet | Ruizhi Guo Lihao Liao Xiaodan Zhao |
| author_sort | Ruizhi Guo |
| collection | DOAJ |
| description | A suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination, syn-dichlorination, oxidative cyclization and asymmetric cyclization have been described. |
| first_indexed | 2024-12-10T14:07:50Z |
| format | Article |
| id | doaj.art-b902e0b95e4d424bab2bff4536c56a89 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-10T14:07:50Z |
| publishDate | 2017-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-b902e0b95e4d424bab2bff4536c56a892022-12-22T01:45:36ZengMDPI AGMolecules1420-30492017-05-0122583510.3390/molecules22050835molecules22050835Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the OxidantsRuizhi Guo0Lihao Liao1Xiaodan Zhao2Institute of Organic Chemistry & MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, ChinaInstitute of Organic Chemistry & MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, ChinaInstitute of Organic Chemistry & MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, ChinaA suitable oxidative system is crucial to electrophilic selenium catalysis (ESC). This short review offers the overview of recent development in ESC with electrophilic N-F reagents as the oxidants. Several highly selective transformations of alkenes such as allylic or vinylic imidation, pyridination, syn-dichlorination, oxidative cyclization and asymmetric cyclization have been described.http://www.mdpi.com/1420-3049/22/5/835alkeneselectrophilic fluorinating reagentsselenium catalysisregioselectivitystereoselectivity |
| spellingShingle | Ruizhi Guo Lihao Liao Xiaodan Zhao Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants Molecules alkenes electrophilic fluorinating reagents selenium catalysis regioselectivity stereoselectivity |
| title | Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants |
| title_full | Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants |
| title_fullStr | Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants |
| title_full_unstemmed | Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants |
| title_short | Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants |
| title_sort | electrophilic selenium catalysis with electrophilic n f reagents as the oxidants |
| topic | alkenes electrophilic fluorinating reagents selenium catalysis regioselectivity stereoselectivity |
| url | http://www.mdpi.com/1420-3049/22/5/835 |
| work_keys_str_mv | AT ruizhiguo electrophilicseleniumcatalysiswithelectrophilicnfreagentsastheoxidants AT lihaoliao electrophilicseleniumcatalysiswithelectrophilicnfreagentsastheoxidants AT xiaodanzhao electrophilicseleniumcatalysiswithelectrophilicnfreagentsastheoxidants |