Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution
The formation of heat stable salts (HSS) during the natural gas sweetening process by amine solvent causes many problems such as corrosion, foaming, capacity reduction, and amine loss. A modeling study was carried out for the removal of HSS ions from amine solution using nanofiltration (NF) membrane...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2021-03-01
|
Series: | Membranes |
Subjects: | |
Online Access: | https://www.mdpi.com/2077-0375/11/4/230 |
_version_ | 1797540109947502592 |
---|---|
author | Asma Ghorbani Behrouz Bayati Enrico Drioli Francesca Macedonio Tavan Kikhavani Mirko Frappa |
author_facet | Asma Ghorbani Behrouz Bayati Enrico Drioli Francesca Macedonio Tavan Kikhavani Mirko Frappa |
author_sort | Asma Ghorbani |
collection | DOAJ |
description | The formation of heat stable salts (HSS) during the natural gas sweetening process by amine solvent causes many problems such as corrosion, foaming, capacity reduction, and amine loss. A modeling study was carried out for the removal of HSS ions from amine solution using nanofiltration (NF) membrane process that ensures the reuse of amine solution for gas sweetening. This model studies the physics of the nanofiltration process by adjusting and investigating pore radius, the effects of membrane charge, and other membrane characteristics. In this paper, the performance of the ternary ions was investigated during the removal process from methyl di-ethanol amine solution by the nanofiltration membrane process. Correlation between feed concentration and permeate concentration, using experimental results with mathematical correlation as C<sub>i,p</sub> = f (C<sub>i,f</sub>) was used in modeling. The results showed that the calculated data from the model provided a good agreement with experimental results (R<sup>2</sup> = 0.90–0.75). Also, the effect of operating conditions (including feed pressure and feed flow rate on ions rejection and recovery ratio across the flat-sheet membrane) was studied. The results showed that the recovery and rejection ratios of the NF membrane depend on the driving pressure across the membrane. While the driving pressure is affected by the feed flow conditions and feed pressure. |
first_indexed | 2024-03-10T12:56:26Z |
format | Article |
id | doaj.art-b92376e596044afba133b9c9f6fda600 |
institution | Directory Open Access Journal |
issn | 2077-0375 |
language | English |
last_indexed | 2024-03-10T12:56:26Z |
publishDate | 2021-03-01 |
publisher | MDPI AG |
record_format | Article |
series | Membranes |
spelling | doaj.art-b92376e596044afba133b9c9f6fda6002023-11-21T11:54:44ZengMDPI AGMembranes2077-03752021-03-0111423010.3390/membranes11040230Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine SolutionAsma Ghorbani0Behrouz Bayati1Enrico Drioli2Francesca Macedonio3Tavan Kikhavani4Mirko Frappa5Department of Chemical Engineering, Ilam University, Ilam 69315-516, IranDepartment of Chemical Engineering, Ilam University, Ilam 69315-516, IranInstitute on Membrane Technology, ITM-CNR, c/o University of Calabria, via P. Bucci, 17/C, 87036 Rende, Cosenza, ItalyInstitute on Membrane Technology, ITM-CNR, c/o University of Calabria, via P. Bucci, 17/C, 87036 Rende, Cosenza, ItalyDepartment of Chemical Engineering, Ilam University, Ilam 69315-516, IranInstitute on Membrane Technology, ITM-CNR, c/o University of Calabria, via P. Bucci, 17/C, 87036 Rende, Cosenza, ItalyThe formation of heat stable salts (HSS) during the natural gas sweetening process by amine solvent causes many problems such as corrosion, foaming, capacity reduction, and amine loss. A modeling study was carried out for the removal of HSS ions from amine solution using nanofiltration (NF) membrane process that ensures the reuse of amine solution for gas sweetening. This model studies the physics of the nanofiltration process by adjusting and investigating pore radius, the effects of membrane charge, and other membrane characteristics. In this paper, the performance of the ternary ions was investigated during the removal process from methyl di-ethanol amine solution by the nanofiltration membrane process. Correlation between feed concentration and permeate concentration, using experimental results with mathematical correlation as C<sub>i,p</sub> = f (C<sub>i,f</sub>) was used in modeling. The results showed that the calculated data from the model provided a good agreement with experimental results (R<sup>2</sup> = 0.90–0.75). Also, the effect of operating conditions (including feed pressure and feed flow rate on ions rejection and recovery ratio across the flat-sheet membrane) was studied. The results showed that the recovery and rejection ratios of the NF membrane depend on the driving pressure across the membrane. While the driving pressure is affected by the feed flow conditions and feed pressure.https://www.mdpi.com/2077-0375/11/4/230gas purificationamine solutionheat stable saltsfeed flownanofiltrationDSPM-DE model |
spellingShingle | Asma Ghorbani Behrouz Bayati Enrico Drioli Francesca Macedonio Tavan Kikhavani Mirko Frappa Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution Membranes gas purification amine solution heat stable salts feed flow nanofiltration DSPM-DE model |
title | Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution |
title_full | Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution |
title_fullStr | Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution |
title_full_unstemmed | Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution |
title_short | Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution |
title_sort | modeling of nanofiltration process using dspm de model for purification of amine solution |
topic | gas purification amine solution heat stable salts feed flow nanofiltration DSPM-DE model |
url | https://www.mdpi.com/2077-0375/11/4/230 |
work_keys_str_mv | AT asmaghorbani modelingofnanofiltrationprocessusingdspmdemodelforpurificationofaminesolution AT behrouzbayati modelingofnanofiltrationprocessusingdspmdemodelforpurificationofaminesolution AT enricodrioli modelingofnanofiltrationprocessusingdspmdemodelforpurificationofaminesolution AT francescamacedonio modelingofnanofiltrationprocessusingdspmdemodelforpurificationofaminesolution AT tavankikhavani modelingofnanofiltrationprocessusingdspmdemodelforpurificationofaminesolution AT mirkofrappa modelingofnanofiltrationprocessusingdspmdemodelforpurificationofaminesolution |