Calculating the absolute adsorption of high-pressure methane on shale by a new method

Currently, many adsorption experiments of methane on shale have been done to understand adsorption characteristics of methane on shale, but those experiments’ pressure and temperature are far less than reservoir pressure and temperature; therefore, we carried out the experiments of methane adsorptio...

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Main Authors: Luo Zuo, Tingxue Jiang, Haitao Wang
Format: Article
Language:English
Published: Hindawi - SAGE Publishing 2020-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617420902658
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author Luo Zuo
Tingxue Jiang
Haitao Wang
author_facet Luo Zuo
Tingxue Jiang
Haitao Wang
author_sort Luo Zuo
collection DOAJ
description Currently, many adsorption experiments of methane on shale have been done to understand adsorption characteristics of methane on shale, but those experiments’ pressure and temperature are far less than reservoir pressure and temperature; therefore, we carried out the experiments of methane adsorption on shale at 75.6°C and 95.6°C with 0–50 MPa pressure range to study the adsorption characteristics of shale under reservoir condition. We also build a new method to calculate the real (absolute) adsorption of methane on shale. Results present that the characteristics of excess adsorption isotherm under high pressure is different from the characteristics of excess isotherm under low pressure; adsorption obtained by adsorption experiment increases with pressure going up until reaching a peak and then declines with further increase in pressure. We build a new method to calculate the absolute adsorption by assuming that the adsorption phase volume approximately equals to the total volume occupied by adsorbed molecule, and the results calculated by our method show this method is reasonable and effective.
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spelling doaj.art-b928c55b971c41968093cecd538945142024-02-22T19:03:23ZengHindawi - SAGE PublishingAdsorption Science & Technology0263-61742048-40382020-03-013810.1177/0263617420902658Calculating the absolute adsorption of high-pressure methane on shale by a new methodLuo ZuoTingxue JiangHaitao WangCurrently, many adsorption experiments of methane on shale have been done to understand adsorption characteristics of methane on shale, but those experiments’ pressure and temperature are far less than reservoir pressure and temperature; therefore, we carried out the experiments of methane adsorption on shale at 75.6°C and 95.6°C with 0–50 MPa pressure range to study the adsorption characteristics of shale under reservoir condition. We also build a new method to calculate the real (absolute) adsorption of methane on shale. Results present that the characteristics of excess adsorption isotherm under high pressure is different from the characteristics of excess isotherm under low pressure; adsorption obtained by adsorption experiment increases with pressure going up until reaching a peak and then declines with further increase in pressure. We build a new method to calculate the absolute adsorption by assuming that the adsorption phase volume approximately equals to the total volume occupied by adsorbed molecule, and the results calculated by our method show this method is reasonable and effective.https://doi.org/10.1177/0263617420902658
spellingShingle Luo Zuo
Tingxue Jiang
Haitao Wang
Calculating the absolute adsorption of high-pressure methane on shale by a new method
Adsorption Science & Technology
title Calculating the absolute adsorption of high-pressure methane on shale by a new method
title_full Calculating the absolute adsorption of high-pressure methane on shale by a new method
title_fullStr Calculating the absolute adsorption of high-pressure methane on shale by a new method
title_full_unstemmed Calculating the absolute adsorption of high-pressure methane on shale by a new method
title_short Calculating the absolute adsorption of high-pressure methane on shale by a new method
title_sort calculating the absolute adsorption of high pressure methane on shale by a new method
url https://doi.org/10.1177/0263617420902658
work_keys_str_mv AT luozuo calculatingtheabsoluteadsorptionofhighpressuremethaneonshalebyanewmethod
AT tingxuejiang calculatingtheabsoluteadsorptionofhighpressuremethaneonshalebyanewmethod
AT haitaowang calculatingtheabsoluteadsorptionofhighpressuremethaneonshalebyanewmethod