Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in Poland

It is supposed that the determination of the content and the mode of occurrence of ecotoxic elements (EE) in feed coal play the most significant role in forecasting distribution of EE in the soil and plants in the vicinity of power stations. Hence, the aim of the work was to analyze the properties o...

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Main Authors: Henryk R. Parzentny, Leokadia Róg
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/11/2/133
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author Henryk R. Parzentny
Leokadia Róg
author_facet Henryk R. Parzentny
Leokadia Róg
author_sort Henryk R. Parzentny
collection DOAJ
description It is supposed that the determination of the content and the mode of occurrence of ecotoxic elements (EE) in feed coal play the most significant role in forecasting distribution of EE in the soil and plants in the vicinity of power stations. Hence, the aim of the work was to analyze the properties of the feed coal, the combustion residues, and the topsoil which are reached by EE together with dust from power stations. The mineral and organic phases, which are the main hosts of EE, were identified by microscopy, X-ray powder diffraction, inductively coupled plasma atomic emission spectrometry, and scanning electron microscope with an energy dispersive X-ray methods. The highest content of elements was observed in the Oi and Oe subhorizons of the topsoil. Their hosts are various types of microspheres and char, emitted by power stations. In the areas of long-term industrial activity, there are also sharp-edged grains of magnetite emitted in the past by zinc, lead, and ironworks. The enrichment of the topsoil with these elements resulted in the increase in the content of EE, by between 0.2 times for Co; and 41.0 times for Cd in the roots of Scots pine, common oak and undergrowth, especially in the rhizodermis and the primary cortex and, more seldom, in the axle roller and cortex cells.
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spelling doaj.art-b92ed6e905d44d5cae5221be11e91fb02023-12-03T15:07:19ZengMDPI AGMinerals2075-163X2021-01-0111213310.3390/min11020133Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in PolandHenryk R. Parzentny0Leokadia Róg1Unemployed, Cooperating with the Institute of Earth Sciences, University of Silesia in Katowice, Będzińska 60, 41-200 Sosnowiec, PolandDepartment of Solid Fuels Quality Assessment, Central Mining Institute, Plac Gwarków 1, 40-166 Katowice, PolandIt is supposed that the determination of the content and the mode of occurrence of ecotoxic elements (EE) in feed coal play the most significant role in forecasting distribution of EE in the soil and plants in the vicinity of power stations. Hence, the aim of the work was to analyze the properties of the feed coal, the combustion residues, and the topsoil which are reached by EE together with dust from power stations. The mineral and organic phases, which are the main hosts of EE, were identified by microscopy, X-ray powder diffraction, inductively coupled plasma atomic emission spectrometry, and scanning electron microscope with an energy dispersive X-ray methods. The highest content of elements was observed in the Oi and Oe subhorizons of the topsoil. Their hosts are various types of microspheres and char, emitted by power stations. In the areas of long-term industrial activity, there are also sharp-edged grains of magnetite emitted in the past by zinc, lead, and ironworks. The enrichment of the topsoil with these elements resulted in the increase in the content of EE, by between 0.2 times for Co; and 41.0 times for Cd in the roots of Scots pine, common oak and undergrowth, especially in the rhizodermis and the primary cortex and, more seldom, in the axle roller and cortex cells.https://www.mdpi.com/2075-163X/11/2/133ecotoxic elementscoalfly ashslagpower stationtopsoil
spellingShingle Henryk R. Parzentny
Leokadia Róg
Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in Poland
Minerals
ecotoxic elements
coal
fly ash
slag
power station
topsoil
title Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in Poland
title_full Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in Poland
title_fullStr Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in Poland
title_full_unstemmed Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in Poland
title_short Distribution and Mode of Occurrence of Co, Ni, Cu, Zn, As, Ag, Cd, Sb, Pb in the Feed Coal, Fly Ash, Slag, in the Topsoil and in the Roots of Trees and Undergrowth Downwind of Three Power Stations in Poland
title_sort distribution and mode of occurrence of co ni cu zn as ag cd sb pb in the feed coal fly ash slag in the topsoil and in the roots of trees and undergrowth downwind of three power stations in poland
topic ecotoxic elements
coal
fly ash
slag
power station
topsoil
url https://www.mdpi.com/2075-163X/11/2/133
work_keys_str_mv AT henrykrparzentny distributionandmodeofoccurrenceofconicuznasagcdsbpbinthefeedcoalflyashslaginthetopsoilandintherootsoftreesandundergrowthdownwindofthreepowerstationsinpoland
AT leokadiarog distributionandmodeofoccurrenceofconicuznasagcdsbpbinthefeedcoalflyashslaginthetopsoilandintherootsoftreesandundergrowthdownwindofthreepowerstationsinpoland