A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking water
Abstract An electrochemical method for detecting the presence of zinc (Zn2+) ions in drinking water was developed using functionalized multi-walled carbon nanotubes (f-MWCNTs) and chitosan (CS). Numerous cylinder-shaped graphene molecules make up f-MWCNTs, which have a high mechanical and electrical...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2022-11-01
|
Series: | Scientific Reports |
Online Access: | https://doi.org/10.1038/s41598-022-21926-6 |
_version_ | 1811328853169143808 |
---|---|
author | Gilbert Ringgit Shafiquzzaman Siddiquee Suryani Saallah Mohammad Tamrin Mohamad Lal |
author_facet | Gilbert Ringgit Shafiquzzaman Siddiquee Suryani Saallah Mohammad Tamrin Mohamad Lal |
author_sort | Gilbert Ringgit |
collection | DOAJ |
description | Abstract An electrochemical method for detecting the presence of zinc (Zn2+) ions in drinking water was developed using functionalized multi-walled carbon nanotubes (f-MWCNTs) and chitosan (CS). Numerous cylinder-shaped graphene molecules make up f-MWCNTs, which have a high mechanical and electrical conductivity. CS benefits from nanomaterials include biocompatibility, biodegradability, and low toxicity, which are excellent in capacity absorption of metal ions. Dangerous levels of metal ions such as zinc are currently present in drinking water as a result of human and natural activity. Zinc toxicity is associated with a variety of disorders, including Alzheimer’s, Parkinson's, diabetes, and cancer. This study incorporated f-MWCNTs and CS with Prussian blue (PB) immobilised on a gold electrode (AuE). Several parameters, including as buffers, pH, scan rate, redox indicator, accumulation time, and volume, were optimised using the cyclic voltammetry (CV) method. According to the CV method, the optimal parameters were phosphate buffered saline (0.1 M, pH 2), 5 mM Prussian blue, 200 mVs-1 scan rate, and 5 s accumulation time. Under ideal circumstances, the differential pulse voltammetry (DPV) method was used to determine the Zn2+ ions concentration range of 0.2–7.0 ppm. The limit of detection (LOD) was 2.60 × 10–7 mol L-1 with a correlation coefficient of R2 = 0.9777. The recovery rate of the developed sensor (f-MWCNTs/CS/PB/AuE) ranged from 95.78 to 98.96%. The developed sensor showed a variety of advantages for detecting Zn2+ in drinking water, including a quick setup process, quick detection, high sensitivity, and mobility. This study developed the essential sensor for monitoring Zn2+ levels in drinking water in the future. |
first_indexed | 2024-04-13T15:33:28Z |
format | Article |
id | doaj.art-b9313b3d18224d049de3b6ac54b81034 |
institution | Directory Open Access Journal |
issn | 2045-2322 |
language | English |
last_indexed | 2024-04-13T15:33:28Z |
publishDate | 2022-11-01 |
publisher | Nature Portfolio |
record_format | Article |
series | Scientific Reports |
spelling | doaj.art-b9313b3d18224d049de3b6ac54b810342022-12-22T02:41:19ZengNature PortfolioScientific Reports2045-23222022-11-0112111410.1038/s41598-022-21926-6A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking waterGilbert Ringgit0Shafiquzzaman Siddiquee1Suryani Saallah2Mohammad Tamrin Mohamad Lal3Biotechnology Research Institute, Universiti Malaysia Sabah, Jalan UMSBiotechnology Research Institute, Universiti Malaysia Sabah, Jalan UMSBiotechnology Research Institute, Universiti Malaysia Sabah, Jalan UMSBorneo Research Marine Institute, University Malaysia Sabah, Jalan UMSAbstract An electrochemical method for detecting the presence of zinc (Zn2+) ions in drinking water was developed using functionalized multi-walled carbon nanotubes (f-MWCNTs) and chitosan (CS). Numerous cylinder-shaped graphene molecules make up f-MWCNTs, which have a high mechanical and electrical conductivity. CS benefits from nanomaterials include biocompatibility, biodegradability, and low toxicity, which are excellent in capacity absorption of metal ions. Dangerous levels of metal ions such as zinc are currently present in drinking water as a result of human and natural activity. Zinc toxicity is associated with a variety of disorders, including Alzheimer’s, Parkinson's, diabetes, and cancer. This study incorporated f-MWCNTs and CS with Prussian blue (PB) immobilised on a gold electrode (AuE). Several parameters, including as buffers, pH, scan rate, redox indicator, accumulation time, and volume, were optimised using the cyclic voltammetry (CV) method. According to the CV method, the optimal parameters were phosphate buffered saline (0.1 M, pH 2), 5 mM Prussian blue, 200 mVs-1 scan rate, and 5 s accumulation time. Under ideal circumstances, the differential pulse voltammetry (DPV) method was used to determine the Zn2+ ions concentration range of 0.2–7.0 ppm. The limit of detection (LOD) was 2.60 × 10–7 mol L-1 with a correlation coefficient of R2 = 0.9777. The recovery rate of the developed sensor (f-MWCNTs/CS/PB/AuE) ranged from 95.78 to 98.96%. The developed sensor showed a variety of advantages for detecting Zn2+ in drinking water, including a quick setup process, quick detection, high sensitivity, and mobility. This study developed the essential sensor for monitoring Zn2+ levels in drinking water in the future.https://doi.org/10.1038/s41598-022-21926-6 |
spellingShingle | Gilbert Ringgit Shafiquzzaman Siddiquee Suryani Saallah Mohammad Tamrin Mohamad Lal A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking water Scientific Reports |
title | A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking water |
title_full | A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking water |
title_fullStr | A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking water |
title_full_unstemmed | A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking water |
title_short | A sensitive and rapid determination of zinc ion (Zn2+) using electrochemical sensor based on f-MWCNTs/CS/PB/AuE in drinking water |
title_sort | sensitive and rapid determination of zinc ion zn2 using electrochemical sensor based on f mwcnts cs pb aue in drinking water |
url | https://doi.org/10.1038/s41598-022-21926-6 |
work_keys_str_mv | AT gilbertringgit asensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater AT shafiquzzamansiddiquee asensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater AT suryanisaallah asensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater AT mohammadtamrinmohamadlal asensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater AT gilbertringgit sensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater AT shafiquzzamansiddiquee sensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater AT suryanisaallah sensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater AT mohammadtamrinmohamadlal sensitiveandrapiddeterminationofzincionzn2usingelectrochemicalsensorbasedonfmwcntscspbaueindrinkingwater |