Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes
Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as mCPBA are employed to in situ generate iodine(III) species. In this...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2018-07-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.14.154 |
| _version_ | 1818919954585485312 |
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| author | Xiang Li Pinhong Chen Guosheng Liu |
| author_facet | Xiang Li Pinhong Chen Guosheng Liu |
| author_sort | Xiang Li |
| collection | DOAJ |
| description | Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as mCPBA are employed to in situ generate iodine(III) species. In this review, recent developments of hypervalent iodine(III)-catalyzed functionalization of alkenes and asymmetric reactions using a chiral iodoarene are summarized. |
| first_indexed | 2024-12-20T01:14:04Z |
| format | Article |
| id | doaj.art-b94fdc1cdf504d96bf685a8f25b67b37 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-20T01:14:04Z |
| publishDate | 2018-07-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-b94fdc1cdf504d96bf685a8f25b67b372022-12-21T19:58:38ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972018-07-011411813182510.3762/bjoc.14.1541860-5397-14-154Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenesXiang Li0Pinhong Chen1Guosheng Liu2State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, ChinaState Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, ChinaState Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, ChinaHypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as mCPBA are employed to in situ generate iodine(III) species. In this review, recent developments of hypervalent iodine(III)-catalyzed functionalization of alkenes and asymmetric reactions using a chiral iodoarene are summarized.https://doi.org/10.3762/bjoc.14.154asymmetric catalysisfunctionalization of alkeneshypervalent iodine(III) |
| spellingShingle | Xiang Li Pinhong Chen Guosheng Liu Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes Beilstein Journal of Organic Chemistry asymmetric catalysis functionalization of alkenes hypervalent iodine(III) |
| title | Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes |
| title_full | Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes |
| title_fullStr | Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes |
| title_full_unstemmed | Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes |
| title_short | Recent advances in hypervalent iodine(III)-catalyzed functionalization of alkenes |
| title_sort | recent advances in hypervalent iodine iii catalyzed functionalization of alkenes |
| topic | asymmetric catalysis functionalization of alkenes hypervalent iodine(III) |
| url | https://doi.org/10.3762/bjoc.14.154 |
| work_keys_str_mv | AT xiangli recentadvancesinhypervalentiodineiiicatalyzedfunctionalizationofalkenes AT pinhongchen recentadvancesinhypervalentiodineiiicatalyzedfunctionalizationofalkenes AT guoshengliu recentadvancesinhypervalentiodineiiicatalyzedfunctionalizationofalkenes |