Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete

The determination of delayed ettringite formation (DEF) in hardened concrete relying simply on the identification of ettringite by electron microscopy or powder X-ray diffractometry can be imperfect because of the high risk of missing other possible deterioration phenomena. The presence of ettringi...

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Main Authors: Y. Ando, H. Shinichi, T. Katayama, K. Torii
Format: Article
Language:English
Published: Consejo Superior de Investigaciones Científicas 2022-04-01
Series:Materiales de Construccion
Subjects:
Online Access:https://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/2921
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author Y. Ando
H. Shinichi
T. Katayama
K. Torii
author_facet Y. Ando
H. Shinichi
T. Katayama
K. Torii
author_sort Y. Ando
collection DOAJ
description The determination of delayed ettringite formation (DEF) in hardened concrete relying simply on the identification of ettringite by electron microscopy or powder X-ray diffractometry can be imperfect because of the high risk of missing other possible deterioration phenomena. The presence of ettringite can be easily biased as an indication of DEF while the actual cause of deterioration is ASR. This paper identifies the deterioration causes and presents different ettringite formation factors based on the petrological observation results. The experiments conditions including depth of carbonation, mix proportions of concrete, curing temperature and others were considered. The deterioration of the samples seem to be correlated to ASR, except for the precast concrete product which presented DEF. In order to determine the deterioration causes and demonstrate the importance of petrological approach, different observations using the same methods were carried out on a concrete specimen blended with fly ash showing some cracks.
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spelling doaj.art-b9707593635c41b8b55c9af2dcfeb3822022-12-22T00:28:53ZengConsejo Superior de Investigaciones CientíficasMateriales de Construccion0465-27461988-32262022-04-017234610.3989/mc.2022.15521Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concreteY. Ando0H. Shinichi1T. Katayama2K. Torii3Taiheiyo Consultant Co. Ltd.Taiheiyo Consultant Co. Ltd.Katayama Petrographic Consulting OfficeKanazawa Branch, Central Nippon Highway Engineering Nagoya Ltd. The determination of delayed ettringite formation (DEF) in hardened concrete relying simply on the identification of ettringite by electron microscopy or powder X-ray diffractometry can be imperfect because of the high risk of missing other possible deterioration phenomena. The presence of ettringite can be easily biased as an indication of DEF while the actual cause of deterioration is ASR. This paper identifies the deterioration causes and presents different ettringite formation factors based on the petrological observation results. The experiments conditions including depth of carbonation, mix proportions of concrete, curing temperature and others were considered. The deterioration of the samples seem to be correlated to ASR, except for the precast concrete product which presented DEF. In order to determine the deterioration causes and demonstrate the importance of petrological approach, different observations using the same methods were carried out on a concrete specimen blended with fly ash showing some cracks. https://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/2921Alkali-silica reactionDelay-ettringite formation (DEF)Scanning electron microscopy (SEM)EttringitePetrography
spellingShingle Y. Ando
H. Shinichi
T. Katayama
K. Torii
Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete
Materiales de Construccion
Alkali-silica reaction
Delay-ettringite formation (DEF)
Scanning electron microscopy (SEM)
Ettringite
Petrography
title Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete
title_full Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete
title_fullStr Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete
title_full_unstemmed Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete
title_short Microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete
title_sort microscopic observations of sites and forms of ettringite in the microstructure of deteriorated concrete
topic Alkali-silica reaction
Delay-ettringite formation (DEF)
Scanning electron microscopy (SEM)
Ettringite
Petrography
url https://materconstrucc.revistas.csic.es/index.php/materconstrucc/article/view/2921
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AT hshinichi microscopicobservationsofsitesandformsofettringiteinthemicrostructureofdeterioratedconcrete
AT tkatayama microscopicobservationsofsitesandformsofettringiteinthemicrostructureofdeterioratedconcrete
AT ktorii microscopicobservationsofsitesandformsofettringiteinthemicrostructureofdeterioratedconcrete