Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater Quality

Contamination of water sources by inappropriately disposed poorly treated wastewater from countryside establishments is a worldwide challenge. This study tested the effectiveness of retrofitting sand (Sa)- and gas−concrete (GC)-packed reactors with biochar (C) in removing turbidity, dissol...

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Main Authors: Ezekiel Kholoma, Agnieszka Renman, Gunno Renman
Format: Article
Language:English
Published: MDPI AG 2020-01-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/10/3/790
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author Ezekiel Kholoma
Agnieszka Renman
Gunno Renman
author_facet Ezekiel Kholoma
Agnieszka Renman
Gunno Renman
author_sort Ezekiel Kholoma
collection DOAJ
description Contamination of water sources by inappropriately disposed poorly treated wastewater from countryside establishments is a worldwide challenge. This study tested the effectiveness of retrofitting sand (Sa)- and gas&#8722;concrete (GC)-packed reactors with biochar (C) in removing turbidity, dissolved organic carbon (DOC), phosphate (PO<sub>4</sub><sup>3&#8722;</sup>), and total phosphorus (P<sub>tot</sub>) from wastewater. The down-flow reactors were each intermittently loaded with 0.063 L/d for 399 days. In general, all reactors achieved &lt;3 NTU (Nephelometric Turbidity Units) effluent turbidity (99% efficiency). GC reactors dominated in inlet PO<sub>4</sub><sup>3&#8722;</sup> (6.1 mg/L) and DOC (25.3 mg/L) reduction, trapping &gt;95% and &gt;60%, respectively. Compared to Sa (PO<sub>4</sub><sup>3&#8722;</sup>: 35%, DOC: 52%), the fortified sand (SaC) filter attenuated more PO<sub>4</sub><sup>3&#8722;</sup> (&gt;42%) and DOC (&gt;58%). Student t-tests revealed that C significantly improved the Sa PO<sub>4</sub><sup>3&#8722;</sup> (<i>p</i> = 0.022) and DOC (<i>p</i> = 0.034) removal efficacy. From regression analysis, 53%, 81%, and 85% PO<sub>4</sub><sup>3&#8722;</sup> sorption variation in Sa, C, and SaC, respectively, were explained by variation in their effluent pH measures. Similarly, a strong linear correlation occurred between PO<sub>4</sub><sup>3&#8722;</sup> sorption efficiency and pH of fortified (r &gt; 0.7) and reference (r = 0.6) GC filters thus suggesting chemisorption mechanisms. Therefore, whereby only sand may be available for treating septic tank effluents, fortifying it with biochar may be a possible measure to improve its efficacy.
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spelling doaj.art-b99dfd38ebbf4e4b89dd3b86b28803752022-12-22T01:56:29ZengMDPI AGApplied Sciences2076-34172020-01-0110379010.3390/app10030790app10030790Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater QualityEzekiel Kholoma0Agnieszka Renman1Gunno Renman2Department of Civil &amp; Environmental Engineering, Botswana International University of Science &amp; Technology, Private Bag 16, Palapye, BotswanaDivision of Water and Environmental Engineering, KTH Royal Institute of Technology, 100 44 Stockholm, SwedenDivision of Water and Environmental Engineering, KTH Royal Institute of Technology, 100 44 Stockholm, SwedenContamination of water sources by inappropriately disposed poorly treated wastewater from countryside establishments is a worldwide challenge. This study tested the effectiveness of retrofitting sand (Sa)- and gas&#8722;concrete (GC)-packed reactors with biochar (C) in removing turbidity, dissolved organic carbon (DOC), phosphate (PO<sub>4</sub><sup>3&#8722;</sup>), and total phosphorus (P<sub>tot</sub>) from wastewater. The down-flow reactors were each intermittently loaded with 0.063 L/d for 399 days. In general, all reactors achieved &lt;3 NTU (Nephelometric Turbidity Units) effluent turbidity (99% efficiency). GC reactors dominated in inlet PO<sub>4</sub><sup>3&#8722;</sup> (6.1 mg/L) and DOC (25.3 mg/L) reduction, trapping &gt;95% and &gt;60%, respectively. Compared to Sa (PO<sub>4</sub><sup>3&#8722;</sup>: 35%, DOC: 52%), the fortified sand (SaC) filter attenuated more PO<sub>4</sub><sup>3&#8722;</sup> (&gt;42%) and DOC (&gt;58%). Student t-tests revealed that C significantly improved the Sa PO<sub>4</sub><sup>3&#8722;</sup> (<i>p</i> = 0.022) and DOC (<i>p</i> = 0.034) removal efficacy. From regression analysis, 53%, 81%, and 85% PO<sub>4</sub><sup>3&#8722;</sup> sorption variation in Sa, C, and SaC, respectively, were explained by variation in their effluent pH measures. Similarly, a strong linear correlation occurred between PO<sub>4</sub><sup>3&#8722;</sup> sorption efficiency and pH of fortified (r &gt; 0.7) and reference (r = 0.6) GC filters thus suggesting chemisorption mechanisms. Therefore, whereby only sand may be available for treating septic tank effluents, fortifying it with biochar may be a possible measure to improve its efficacy.https://www.mdpi.com/2076-3417/10/3/790wastewater treatmentbiocharpacked bed reactorfortificationphosphorusdissolved organic carbon
spellingShingle Ezekiel Kholoma
Agnieszka Renman
Gunno Renman
Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater Quality
Applied Sciences
wastewater treatment
biochar
packed bed reactor
fortification
phosphorus
dissolved organic carbon
title Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater Quality
title_full Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater Quality
title_fullStr Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater Quality
title_full_unstemmed Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater Quality
title_short Filter Media-Packed Bed Reactor Fortification with Biochar to Enhance Wastewater Quality
title_sort filter media packed bed reactor fortification with biochar to enhance wastewater quality
topic wastewater treatment
biochar
packed bed reactor
fortification
phosphorus
dissolved organic carbon
url https://www.mdpi.com/2076-3417/10/3/790
work_keys_str_mv AT ezekielkholoma filtermediapackedbedreactorfortificationwithbiochartoenhancewastewaterquality
AT agnieszkarenman filtermediapackedbedreactorfortificationwithbiochartoenhancewastewaterquality
AT gunnorenman filtermediapackedbedreactorfortificationwithbiochartoenhancewastewaterquality