Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City
Total suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high...
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Springer
2016-06-01
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Series: | Asian Journal of Atmospheric Environment |
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Online Access: | http://asianjae.org/_common/do.php?a=full&b=11&bidx=1490&aidx=19045 |
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author | Kazuichi Hayakawa Ning Tang Hiroshi Morisaki Akira Toriba Tomoko Akutagawa Shigekatsu Sakai |
author_facet | Kazuichi Hayakawa Ning Tang Hiroshi Morisaki Akira Toriba Tomoko Akutagawa Shigekatsu Sakai |
author_sort | Kazuichi Hayakawa |
collection | DOAJ |
description | Total suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high-performance liquid chromatography (HPLC) using fluorescence and chemiluminescence detectors, respectively. No relationship was observed between the atmospheric PAH and NPAH concentration, or the atmospheric PAH and TSP concentration. However, there was a tendency that the atmospheric PAH concentration was higher when the wind blew from the coke-oven plant. Furthermore, the concentration ratios of 1-nitropyrene to pyrene, which is a suitable indicator of the contribution made by automobiles and coal combustion systems to urban air particulates, were smaller in Muroran and the values were close to those observed in particulates from coal combustion systems. Therefore, these results show that the PAH and NPAH compositions for Muroran are characteristic of an iron-manufacturing city. |
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institution | Directory Open Access Journal |
issn | 1976-6912 2287-1160 |
language | English |
last_indexed | 2024-03-12T07:12:30Z |
publishDate | 2016-06-01 |
publisher | Springer |
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series | Asian Journal of Atmospheric Environment |
spelling | doaj.art-b9a91da1d11f40a7b9414793731f293e2023-09-02T23:03:04ZengSpringerAsian Journal of Atmospheric Environment1976-69122287-11602016-06-01102909810.5572/ajae.2016.10.2.090Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing CityKazuichi Hayakawa0Ning Tang1Hiroshi Morisaki2Akira Toriba3Tomoko Akutagawa4Shigekatsu Sakai5Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanFaculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanFaculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanFaculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanHokkaido Institute of Environmental Sciences, Kita 19 jo, Nishi 12 chome, Kita-ku, Sapporo 060-0819, JapanHokkaido Institute of Environmental Sciences, Kita 19 jo, Nishi 12 chome, Kita-ku, Sapporo 060-0819, JapanTotal suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high-performance liquid chromatography (HPLC) using fluorescence and chemiluminescence detectors, respectively. No relationship was observed between the atmospheric PAH and NPAH concentration, or the atmospheric PAH and TSP concentration. However, there was a tendency that the atmospheric PAH concentration was higher when the wind blew from the coke-oven plant. Furthermore, the concentration ratios of 1-nitropyrene to pyrene, which is a suitable indicator of the contribution made by automobiles and coal combustion systems to urban air particulates, were smaller in Muroran and the values were close to those observed in particulates from coal combustion systems. Therefore, these results show that the PAH and NPAH compositions for Muroran are characteristic of an iron-manufacturing city.http://asianjae.org/_common/do.php?a=full&b=11&bidx=1490&aidx=19045polycyclic aromatic hydrocarbonnitropolycyclic aromatic hydrocarbonairborne particulatescoke-oven plantiron manufacture |
spellingShingle | Kazuichi Hayakawa Ning Tang Hiroshi Morisaki Akira Toriba Tomoko Akutagawa Shigekatsu Sakai Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City Asian Journal of Atmospheric Environment polycyclic aromatic hydrocarbon nitropolycyclic aromatic hydrocarbon airborne particulates coke-oven plant iron manufacture |
title | Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City |
title_full | Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City |
title_fullStr | Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City |
title_full_unstemmed | Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City |
title_short | Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City |
title_sort | atmospheric polycyclic and nitropolycyclic aromatic hydrocarbons in an iron manufacturing city |
topic | polycyclic aromatic hydrocarbon nitropolycyclic aromatic hydrocarbon airborne particulates coke-oven plant iron manufacture |
url | http://asianjae.org/_common/do.php?a=full&b=11&bidx=1490&aidx=19045 |
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