Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City

Total suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high...

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Main Authors: Kazuichi Hayakawa, Ning Tang, Hiroshi Morisaki, Akira Toriba, Tomoko Akutagawa, Shigekatsu Sakai
Format: Article
Language:English
Published: Springer 2016-06-01
Series:Asian Journal of Atmospheric Environment
Subjects:
Online Access:http://asianjae.org/_common/do.php?a=full&b=11&bidx=1490&aidx=19045
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author Kazuichi Hayakawa
Ning Tang
Hiroshi Morisaki
Akira Toriba
Tomoko Akutagawa
Shigekatsu Sakai
author_facet Kazuichi Hayakawa
Ning Tang
Hiroshi Morisaki
Akira Toriba
Tomoko Akutagawa
Shigekatsu Sakai
author_sort Kazuichi Hayakawa
collection DOAJ
description Total suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high-performance liquid chromatography (HPLC) using fluorescence and chemiluminescence detectors, respectively. No relationship was observed between the atmospheric PAH and NPAH concentration, or the atmospheric PAH and TSP concentration. However, there was a tendency that the atmospheric PAH concentration was higher when the wind blew from the coke-oven plant. Furthermore, the concentration ratios of 1-nitropyrene to pyrene, which is a suitable indicator of the contribution made by automobiles and coal combustion systems to urban air particulates, were smaller in Muroran and the values were close to those observed in particulates from coal combustion systems. Therefore, these results show that the PAH and NPAH compositions for Muroran are characteristic of an iron-manufacturing city.
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spelling doaj.art-b9a91da1d11f40a7b9414793731f293e2023-09-02T23:03:04ZengSpringerAsian Journal of Atmospheric Environment1976-69122287-11602016-06-01102909810.5572/ajae.2016.10.2.090Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing CityKazuichi Hayakawa0Ning Tang1Hiroshi Morisaki2Akira Toriba3Tomoko Akutagawa4Shigekatsu Sakai5Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanFaculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanFaculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanFaculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, JapanHokkaido Institute of Environmental Sciences, Kita 19 jo, Nishi 12 chome, Kita-ku, Sapporo 060-0819, JapanHokkaido Institute of Environmental Sciences, Kita 19 jo, Nishi 12 chome, Kita-ku, Sapporo 060-0819, JapanTotal suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high-performance liquid chromatography (HPLC) using fluorescence and chemiluminescence detectors, respectively. No relationship was observed between the atmospheric PAH and NPAH concentration, or the atmospheric PAH and TSP concentration. However, there was a tendency that the atmospheric PAH concentration was higher when the wind blew from the coke-oven plant. Furthermore, the concentration ratios of 1-nitropyrene to pyrene, which is a suitable indicator of the contribution made by automobiles and coal combustion systems to urban air particulates, were smaller in Muroran and the values were close to those observed in particulates from coal combustion systems. Therefore, these results show that the PAH and NPAH compositions for Muroran are characteristic of an iron-manufacturing city.http://asianjae.org/_common/do.php?a=full&b=11&bidx=1490&aidx=19045polycyclic aromatic hydrocarbonnitropolycyclic aromatic hydrocarbonairborne particulatescoke-oven plantiron manufacture
spellingShingle Kazuichi Hayakawa
Ning Tang
Hiroshi Morisaki
Akira Toriba
Tomoko Akutagawa
Shigekatsu Sakai
Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City
Asian Journal of Atmospheric Environment
polycyclic aromatic hydrocarbon
nitropolycyclic aromatic hydrocarbon
airborne particulates
coke-oven plant
iron manufacture
title Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City
title_full Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City
title_fullStr Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City
title_full_unstemmed Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City
title_short Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Iron-manufacturing City
title_sort atmospheric polycyclic and nitropolycyclic aromatic hydrocarbons in an iron manufacturing city
topic polycyclic aromatic hydrocarbon
nitropolycyclic aromatic hydrocarbon
airborne particulates
coke-oven plant
iron manufacture
url http://asianjae.org/_common/do.php?a=full&b=11&bidx=1490&aidx=19045
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