Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal Applications

Exploiting solar energy using photo-thermal (PT) and/or hybridised photovoltaic/thermal (PVT) systems can represent a viable alternative to the growing demand for renewable energy. For large-scale implementation, such systems require thermal fluids able to enhance the combined conversion efficiency...

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Main Authors: James Walshe, Pauraic Mc Carron, Conor McLoughlin, Sarah McCormack, John Doran, George Amarandei
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/6/1201
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author James Walshe
Pauraic Mc Carron
Conor McLoughlin
Sarah McCormack
John Doran
George Amarandei
author_facet James Walshe
Pauraic Mc Carron
Conor McLoughlin
Sarah McCormack
John Doran
George Amarandei
author_sort James Walshe
collection DOAJ
description Exploiting solar energy using photo-thermal (PT) and/or hybridised photovoltaic/thermal (PVT) systems can represent a viable alternative to the growing demand for renewable energy. For large-scale implementation, such systems require thermal fluids able to enhance the combined conversion efficiency achievable by controlling the ‘thermal’ and ‘electrical’ components of the solar spectrum. Nanofluids are typically employed for these purposes and they should exhibit high heat-transfer capabilities and optical properties tuned towards the peak performance spectral window of the photovoltaic (PV) component. In this work, novel nanofluids, composed of highly luminescent organic molecules and Ag nanoparticles dispersed within a base fluid, were tested for PT and PVT applications. These nanofluids were designed to mimic the behaviour of luminescent down-shifting molecules while offering enhanced thermo-physical characteristics over the host base fluid. The nanofluids’ conversion efficiency was evaluated under a standard AM1.5G weighted solar spectrum. The results revealed that the Ag nanoparticles’ inclusion in the composite fluid has the potential to improve the total solar energy conversion. The nanoparticles’ presence minimizes the losses in the electrical power component of the PVT systems as the thermal conversion increases. The enhanced performances recorded suggest that these nanofluids could represent suitable candidates for solar energy conversion applications.
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spelling doaj.art-b9af0a9801dc4840a743a0345e9521a32023-11-20T04:24:53ZengMDPI AGNanomaterials2079-49912020-06-01106120110.3390/nano10061201Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal ApplicationsJames Walshe0Pauraic Mc Carron1Conor McLoughlin2Sarah McCormack3John Doran4George Amarandei5School of Physics & Clinical & Optometric Sciences, Technological University Dublin, City Campus, Kevin Street, D08 NF82 Dublin, IrelandSchool of Science & Computing, Technological University Dublin, Tallaght Campus, D08 NF82 Dublin, IrelandSchool of Physics & Clinical & Optometric Sciences, Technological University Dublin, City Campus, Kevin Street, D08 NF82 Dublin, IrelandDepartment of Civil, Structural & Environmental Engineering, Trinity College Dublin, D08 NF82 Dublin, IrelandSchool of Physics & Clinical & Optometric Sciences, Technological University Dublin, City Campus, Kevin Street, D08 NF82 Dublin, IrelandSchool of Physics & Clinical & Optometric Sciences, Technological University Dublin, City Campus, Kevin Street, D08 NF82 Dublin, IrelandExploiting solar energy using photo-thermal (PT) and/or hybridised photovoltaic/thermal (PVT) systems can represent a viable alternative to the growing demand for renewable energy. For large-scale implementation, such systems require thermal fluids able to enhance the combined conversion efficiency achievable by controlling the ‘thermal’ and ‘electrical’ components of the solar spectrum. Nanofluids are typically employed for these purposes and they should exhibit high heat-transfer capabilities and optical properties tuned towards the peak performance spectral window of the photovoltaic (PV) component. In this work, novel nanofluids, composed of highly luminescent organic molecules and Ag nanoparticles dispersed within a base fluid, were tested for PT and PVT applications. These nanofluids were designed to mimic the behaviour of luminescent down-shifting molecules while offering enhanced thermo-physical characteristics over the host base fluid. The nanofluids’ conversion efficiency was evaluated under a standard AM1.5G weighted solar spectrum. The results revealed that the Ag nanoparticles’ inclusion in the composite fluid has the potential to improve the total solar energy conversion. The nanoparticles’ presence minimizes the losses in the electrical power component of the PVT systems as the thermal conversion increases. The enhanced performances recorded suggest that these nanofluids could represent suitable candidates for solar energy conversion applications.https://www.mdpi.com/2079-4991/10/6/1201luminescent down shiftingthermal energyphotovoltaicsfluorescencespectral beam splittingnanomaterials
spellingShingle James Walshe
Pauraic Mc Carron
Conor McLoughlin
Sarah McCormack
John Doran
George Amarandei
Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal Applications
Nanomaterials
luminescent down shifting
thermal energy
photovoltaics
fluorescence
spectral beam splitting
nanomaterials
title Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal Applications
title_full Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal Applications
title_fullStr Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal Applications
title_full_unstemmed Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal Applications
title_short Nanofluid Development Using Silver Nanoparticles and Organic-Luminescent Molecules for Solar-Thermal and Hybrid Photovoltaic-Thermal Applications
title_sort nanofluid development using silver nanoparticles and organic luminescent molecules for solar thermal and hybrid photovoltaic thermal applications
topic luminescent down shifting
thermal energy
photovoltaics
fluorescence
spectral beam splitting
nanomaterials
url https://www.mdpi.com/2079-4991/10/6/1201
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