Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence
Intramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ∼1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents.
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
EDP Sciences
2013-03-01
|
Series: | EPJ Web of Conferences |
Online Access: | http://dx.doi.org/10.1051/epjconf/20134105023 |
_version_ | 1818888921587646464 |
---|---|
author | Joo Taiha Rhee Y. H. Im D. Young Kim So Park Myeongkee |
author_facet | Joo Taiha Rhee Y. H. Im D. Young Kim So Park Myeongkee |
author_sort | Joo Taiha |
collection | DOAJ |
description | Intramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ∼1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents. |
first_indexed | 2024-12-19T17:00:48Z |
format | Article |
id | doaj.art-b9c247c4c3d74fe692205657576087a9 |
institution | Directory Open Access Journal |
issn | 2100-014X |
language | English |
last_indexed | 2024-12-19T17:00:48Z |
publishDate | 2013-03-01 |
publisher | EDP Sciences |
record_format | Article |
series | EPJ Web of Conferences |
spelling | doaj.art-b9c247c4c3d74fe692205657576087a92022-12-21T20:13:18ZengEDP SciencesEPJ Web of Conferences2100-014X2013-03-01410502310.1051/epjconf/20134105023Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved FluorescenceJoo TaihaRhee Y. H.Im D.Young Kim SoPark MyeongkeeIntramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ∼1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents.http://dx.doi.org/10.1051/epjconf/20134105023 |
spellingShingle | Joo Taiha Rhee Y. H. Im D. Young Kim So Park Myeongkee Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence EPJ Web of Conferences |
title | Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence |
title_full | Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence |
title_fullStr | Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence |
title_full_unstemmed | Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence |
title_short | Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence |
title_sort | intramolecular charge transfer dynamics of a planarized analogue of 4 dimethylamino benzonitrile dmabn by time resolved fluorescence |
url | http://dx.doi.org/10.1051/epjconf/20134105023 |
work_keys_str_mv | AT jootaiha intramolecularchargetransferdynamicsofaplanarizedanalogueof4dimethylaminobenzonitriledmabnbytimeresolvedfluorescence AT rheeyh intramolecularchargetransferdynamicsofaplanarizedanalogueof4dimethylaminobenzonitriledmabnbytimeresolvedfluorescence AT imd intramolecularchargetransferdynamicsofaplanarizedanalogueof4dimethylaminobenzonitriledmabnbytimeresolvedfluorescence AT youngkimso intramolecularchargetransferdynamicsofaplanarizedanalogueof4dimethylaminobenzonitriledmabnbytimeresolvedfluorescence AT parkmyeongkee intramolecularchargetransferdynamicsofaplanarizedanalogueof4dimethylaminobenzonitriledmabnbytimeresolvedfluorescence |