Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature
The effect of temperature on the adsorption of benzene on the nascent surface of steel was examined. Cutting tests were carried out under high vacuum condition. The components adsorbed onto or desorbed from the nascent surfaces formed by cutting were monitored by a quadrupole mass spectrometer. The...
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| Format: | Article |
| Language: | English |
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Japanese Society of Tribologists
2012-04-01
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| Series: | Tribology Online |
| Subjects: | |
| Online Access: | https://www.jstage.jst.go.jp/article/trol/7/2/7_2_54/_pdf/-char/en |
| _version_ | 1818683979261280256 |
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| author | Naoshi Shimotomai Hidetaka Nanao Shigeyuki Mori |
| author_facet | Naoshi Shimotomai Hidetaka Nanao Shigeyuki Mori |
| author_sort | Naoshi Shimotomai |
| collection | DOAJ |
| description | The effect of temperature on the adsorption of benzene on the nascent surface of steel was examined. Cutting tests were carried out under high vacuum condition. The components adsorbed onto or desorbed from the nascent surfaces formed by cutting were monitored by a quadrupole mass spectrometer. The adsorption rate of benzene decreased with increasing temperature whereas desorption rate of hydrogen and adsorption rate of water increased. It appeared that water from residual gas preferentially adsorbed onto the nascent surface to disturb benzene adsorption as the temperature increased where the water was decomposed to form hydrogen. In this study, it was found that the reaction of adsorption on mechanically formed nascent surfaces is affected by temperature. Adsorption activity of mechanically formed nascent surfaces was calculated. |
| first_indexed | 2024-12-17T10:43:20Z |
| format | Article |
| id | doaj.art-b9f61627250546208094ed65755c5b22 |
| institution | Directory Open Access Journal |
| issn | 1881-2198 |
| language | English |
| last_indexed | 2024-12-17T10:43:20Z |
| publishDate | 2012-04-01 |
| publisher | Japanese Society of Tribologists |
| record_format | Article |
| series | Tribology Online |
| spelling | doaj.art-b9f61627250546208094ed65755c5b222022-12-21T21:52:11ZengJapanese Society of TribologistsTribology Online1881-21982012-04-0172545910.2474/trol.7.54trolTribochemical Reaction of Benzene on Nascent Steel Surface and Effect of TemperatureNaoshi Shimotomai0Hidetaka Nanao1Shigeyuki Mori2Department of Metalworking Fluid Technology, Kyodoyushi Co., LtdDepartment of Chemistry and Bioengineering, Faculty of Engineering, Iwate UniversityDepartment of Chemistry and Bioengineering, Faculty of Engineering, Iwate UniversityThe effect of temperature on the adsorption of benzene on the nascent surface of steel was examined. Cutting tests were carried out under high vacuum condition. The components adsorbed onto or desorbed from the nascent surfaces formed by cutting were monitored by a quadrupole mass spectrometer. The adsorption rate of benzene decreased with increasing temperature whereas desorption rate of hydrogen and adsorption rate of water increased. It appeared that water from residual gas preferentially adsorbed onto the nascent surface to disturb benzene adsorption as the temperature increased where the water was decomposed to form hydrogen. In this study, it was found that the reaction of adsorption on mechanically formed nascent surfaces is affected by temperature. Adsorption activity of mechanically formed nascent surfaces was calculated.https://www.jstage.jst.go.jp/article/trol/7/2/7_2_54/_pdf/-char/ennascent surfacetribochemical reactionadsorptiondecompositiontemperature |
| spellingShingle | Naoshi Shimotomai Hidetaka Nanao Shigeyuki Mori Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature Tribology Online nascent surface tribochemical reaction adsorption decomposition temperature |
| title | Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature |
| title_full | Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature |
| title_fullStr | Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature |
| title_full_unstemmed | Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature |
| title_short | Tribochemical Reaction of Benzene on Nascent Steel Surface and Effect of Temperature |
| title_sort | tribochemical reaction of benzene on nascent steel surface and effect of temperature |
| topic | nascent surface tribochemical reaction adsorption decomposition temperature |
| url | https://www.jstage.jst.go.jp/article/trol/7/2/7_2_54/_pdf/-char/en |
| work_keys_str_mv | AT naoshishimotomai tribochemicalreactionofbenzeneonnascentsteelsurfaceandeffectoftemperature AT hidetakananao tribochemicalreactionofbenzeneonnascentsteelsurfaceandeffectoftemperature AT shigeyukimori tribochemicalreactionofbenzeneonnascentsteelsurfaceandeffectoftemperature |