Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere
A series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)] (X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2004-12-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol69/No12/V69-No12-07.pdf |
| _version_ | 1818826840694849536 |
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| author | MAREK PAVLICEK ZDENEK SINDALAR MICHAL MALON RICHARD PASTOREK JOSEF HUSAREK |
| author_facet | MAREK PAVLICEK ZDENEK SINDALAR MICHAL MALON RICHARD PASTOREK JOSEF HUSAREK |
| author_sort | MAREK PAVLICEK |
| collection | DOAJ |
| description | A series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)] (X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H}-NMR spectroscopy, thermal analysis, magnetochemical and conductivity measurements. On the basis of the results of the physico-chemical study, all complexes are diamagnetic, non-electrolytes, with a square-planar NiS2PX chromophore. |
| first_indexed | 2024-12-19T00:34:03Z |
| format | Article |
| id | doaj.art-ba396cacdc744c65a896e6c1d142260e |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-19T00:34:03Z |
| publishDate | 2004-12-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-ba396cacdc744c65a896e6c1d142260e2022-12-21T20:44:55ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392004-12-01691210531061Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphereMAREK PAVLICEKZDENEK SINDALARMICHAL MALONRICHARD PASTOREKJOSEF HUSAREKA series of new Ni(II) dithiocarbamate compounds of the composition [NiX(cetdtc)(PR3)] (X = Cl, Br, I, NCS; cetdtc = cyclohexylethyldithiocarbamate; R = phenyl, n-butyl) has been synthesized. All the isolated complexes have been characterized by elemental analysis, IR and UV/VIS spectroscopy, 31P{1H}-NMR spectroscopy, thermal analysis, magnetochemical and conductivity measurements. On the basis of the results of the physico-chemical study, all complexes are diamagnetic, non-electrolytes, with a square-planar NiS2PX chromophore.http://www.shd.org.yu/HtDocs/SHD/Vol69/No12/V69-No12-07.pdfnickel(II) cyclohexylethyldithiocarbamate complexesmonodantate P-donor ligandssynthesis31P{1H}-NMR spectroscopy |
| spellingShingle | MAREK PAVLICEK ZDENEK SINDALAR MICHAL MALON RICHARD PASTOREK JOSEF HUSAREK Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere Journal of the Serbian Chemical Society nickel(II) cyclohexylethyldithiocarbamate complexes monodantate P-donor ligands synthesis 31P{1H}-NMR spectroscopy |
| title | Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere |
| title_full | Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere |
| title_fullStr | Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere |
| title_full_unstemmed | Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere |
| title_short | Nickel(II) cyclohexylethyldithiocarbamate complexes with monodentate P-donor ligands in the coordination sphere |
| title_sort | nickel ii cyclohexylethyldithiocarbamate complexes with monodentate p donor ligands in the coordination sphere |
| topic | nickel(II) cyclohexylethyldithiocarbamate complexes monodantate P-donor ligands synthesis 31P{1H}-NMR spectroscopy |
| url | http://www.shd.org.yu/HtDocs/SHD/Vol69/No12/V69-No12-07.pdf |
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