Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigations

The environmental concerns and government regulations have led to a surge in preparation of biodiesels as one of the main components for renewable and alternative fuels from cost effective biowastes. The degradation of biodiesel during storage produces organic acids that could lead to the corrosion...

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Main Authors: K.K Adama, I.B Onyeachu, L.U Modebe, V.I Chukwuike, P.O Oghuma, C.E Akhabue
Format: Article
Language:English
Published: Elsevier 2024-03-01
Series:Results in Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590123023008228
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author K.K Adama
I.B Onyeachu
L.U Modebe
V.I Chukwuike
P.O Oghuma
C.E Akhabue
author_facet K.K Adama
I.B Onyeachu
L.U Modebe
V.I Chukwuike
P.O Oghuma
C.E Akhabue
author_sort K.K Adama
collection DOAJ
description The environmental concerns and government regulations have led to a surge in preparation of biodiesels as one of the main components for renewable and alternative fuels from cost effective biowastes. The degradation of biodiesel during storage produces organic acids that could lead to the corrosion of component parts of the engine thus it is imperative to define the rate of corrosivity of this golden alternative before its application. The current study utilizes electrochemical methods (OCP, EIS and PDP) in addition to advanced techniques such as SEM, UV–vis and FTIR to investigate the comparative corrosion behaviour of three biodiesels namely; jatropha oil biodiesel (JOB), neem oil biodiesel (NOB) and waste cooking oil biodiesel (WCOB) on carbon steel. The surface morphology of the post corrosion steel samples as characterized by SEM revealed differences in surface damage due to corrosion in the various systems. The study further inferred that the investigated biodiesel requires specific carbon steel component type for compatibility and effectiveness in fuel delivery and storage systems of automobile engines which were evident by the different corrosion degradation rates (103, 74 and 51 mpy) for JOB, NOB and WCOB respectively. The overall results showed differential corrosion rates of the order JOB > NOB > WCOB on carbon steel under similar experimental conditions.
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spelling doaj.art-ba39aceb23934d7da5ab50db87f49fe92024-03-24T07:00:15ZengElsevierResults in Engineering2590-12302024-03-0121101695Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigationsK.K Adama0I.B Onyeachu1L.U Modebe2V.I Chukwuike3P.O Oghuma4C.E Akhabue5Department of Chemical Engineering, Faculty of Engineering, Edo State University Uzairue, Edo State, Nigeria; Corresponding author.Department of Industrial Chemistry, Faculty of Science, Edo State University Uzairue, Edo State, NigeriaDepartment of Chemical Engineering, Faculty of Engineering, University of Delta, Agbor, Delta State, NigeriaDepartment of Industrial Chemistry, Faculty of Science, Federal University of Health Science, Uburu, Ebonyi State, Nigeria; Corresponding author.Department of Chemical Engineering, Faculty of Engineering, Edo State University Uzairue, Edo State, NigeriaDepartment of Chemical Engineering, Faculty of Engineering, University of Benin, Benin-city, Edo State, NigeriaThe environmental concerns and government regulations have led to a surge in preparation of biodiesels as one of the main components for renewable and alternative fuels from cost effective biowastes. The degradation of biodiesel during storage produces organic acids that could lead to the corrosion of component parts of the engine thus it is imperative to define the rate of corrosivity of this golden alternative before its application. The current study utilizes electrochemical methods (OCP, EIS and PDP) in addition to advanced techniques such as SEM, UV–vis and FTIR to investigate the comparative corrosion behaviour of three biodiesels namely; jatropha oil biodiesel (JOB), neem oil biodiesel (NOB) and waste cooking oil biodiesel (WCOB) on carbon steel. The surface morphology of the post corrosion steel samples as characterized by SEM revealed differences in surface damage due to corrosion in the various systems. The study further inferred that the investigated biodiesel requires specific carbon steel component type for compatibility and effectiveness in fuel delivery and storage systems of automobile engines which were evident by the different corrosion degradation rates (103, 74 and 51 mpy) for JOB, NOB and WCOB respectively. The overall results showed differential corrosion rates of the order JOB > NOB > WCOB on carbon steel under similar experimental conditions.http://www.sciencedirect.com/science/article/pii/S2590123023008228Biodiesel corrosionC1020 steelCorrosion behaviourElectrochemical testsSEM
spellingShingle K.K Adama
I.B Onyeachu
L.U Modebe
V.I Chukwuike
P.O Oghuma
C.E Akhabue
Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigations
Results in Engineering
Biodiesel corrosion
C1020 steel
Corrosion behaviour
Electrochemical tests
SEM
title Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigations
title_full Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigations
title_fullStr Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigations
title_full_unstemmed Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigations
title_short Comparative evaluation of corrosion behaviour of carbon steel (C1020) in different biodiesels: Synthesis, characterization and electrochemical investigations
title_sort comparative evaluation of corrosion behaviour of carbon steel c1020 in different biodiesels synthesis characterization and electrochemical investigations
topic Biodiesel corrosion
C1020 steel
Corrosion behaviour
Electrochemical tests
SEM
url http://www.sciencedirect.com/science/article/pii/S2590123023008228
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