Injection Molded PP Foams Using Food Ingredients for Food Packaging Applications

A new approach to the creation of polypropylene (PP) based foaming materials was developed using food grade foaming agents that were coated on the PP pellets. More specifically, sodium bicarbonate and organic acids were used to coat PP pellets using either polyethyleneoxide (PEO) or lipid esters as...

Full description

Bibliographic Details
Main Authors: Artemis Tsagdi, Ioannis Drossos, Despoina Georgiou, Stylianos Exarhopoulos, Georgios Karasiotas, Joannis K. Kallitsis, Eleni P. Kalogianni
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/2/288
_version_ 1797410447796731904
author Artemis Tsagdi
Ioannis Drossos
Despoina Georgiou
Stylianos Exarhopoulos
Georgios Karasiotas
Joannis K. Kallitsis
Eleni P. Kalogianni
author_facet Artemis Tsagdi
Ioannis Drossos
Despoina Georgiou
Stylianos Exarhopoulos
Georgios Karasiotas
Joannis K. Kallitsis
Eleni P. Kalogianni
author_sort Artemis Tsagdi
collection DOAJ
description A new approach to the creation of polypropylene (PP) based foaming materials was developed using food grade foaming agents that were coated on the PP pellets. More specifically, sodium bicarbonate and organic acids were used to coat PP pellets using either polyethyleneoxide (PEO) or lipid esters as coating stabilizers. In order to overcome the problem of the thermal decomposition of sodium bicarbonate at temperatures lower than the PP melting temperature, which makes the direct foaming during melt mixing impossible, the proposed methodology was proved quite efficient. Thus, new PP masterbatches were prepared, where the foaming agents were incorporated as coating at PP pellets at contents up to 10%, and initially used in Lab scale injection machines in order to find the best combination of materials that resulted in the production of foamed articles. Subsequently selected material combinations were tested in an industrial scale injection molding machine, where an optimization of the injection parameters was attempted. The outcome of this was the production of PP articles with significantly increased void fraction, up to 14%, decreased thermal conductivity, up to 20%, and various pore sizes as was observed via microscopic examination using SEM and CLSM.
first_indexed 2024-03-09T04:30:09Z
format Article
id doaj.art-ba5d8eae03aa4d0c8c1e6829f6391df4
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-09T04:30:09Z
publishDate 2021-01-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-ba5d8eae03aa4d0c8c1e6829f6391df42023-12-03T13:37:05ZengMDPI AGPolymers2073-43602021-01-0113228810.3390/polym13020288Injection Molded PP Foams Using Food Ingredients for Food Packaging ApplicationsArtemis Tsagdi0Ioannis Drossos1Despoina Georgiou2Stylianos Exarhopoulos3Georgios Karasiotas4Joannis K. Kallitsis5Eleni P. Kalogianni6Department of Chemistry, University of Patras, GR-26504 Patras, GreeceThrace Plastics Pack S.A., Member of Thrace Group Companies, GR-67100 Magiko Xanthi, GreeceDepartment of Food Science and Technology, International Hellenic University, GR-57001 Thermi, GreeceDepartment of Food Science and Technology, International Hellenic University, GR-57001 Thermi, GreeceThrace Plastics Pack S.A., Member of Thrace Group Companies, GR-67100 Magiko Xanthi, GreeceDepartment of Chemistry, University of Patras, GR-26504 Patras, GreeceDepartment of Food Science and Technology, International Hellenic University, GR-57001 Thermi, GreeceA new approach to the creation of polypropylene (PP) based foaming materials was developed using food grade foaming agents that were coated on the PP pellets. More specifically, sodium bicarbonate and organic acids were used to coat PP pellets using either polyethyleneoxide (PEO) or lipid esters as coating stabilizers. In order to overcome the problem of the thermal decomposition of sodium bicarbonate at temperatures lower than the PP melting temperature, which makes the direct foaming during melt mixing impossible, the proposed methodology was proved quite efficient. Thus, new PP masterbatches were prepared, where the foaming agents were incorporated as coating at PP pellets at contents up to 10%, and initially used in Lab scale injection machines in order to find the best combination of materials that resulted in the production of foamed articles. Subsequently selected material combinations were tested in an industrial scale injection molding machine, where an optimization of the injection parameters was attempted. The outcome of this was the production of PP articles with significantly increased void fraction, up to 14%, decreased thermal conductivity, up to 20%, and various pore sizes as was observed via microscopic examination using SEM and CLSM.https://www.mdpi.com/2073-4360/13/2/288polypropylenecoating processfoamed PPfoaming agentsfood ingredients
spellingShingle Artemis Tsagdi
Ioannis Drossos
Despoina Georgiou
Stylianos Exarhopoulos
Georgios Karasiotas
Joannis K. Kallitsis
Eleni P. Kalogianni
Injection Molded PP Foams Using Food Ingredients for Food Packaging Applications
Polymers
polypropylene
coating process
foamed PP
foaming agents
food ingredients
title Injection Molded PP Foams Using Food Ingredients for Food Packaging Applications
title_full Injection Molded PP Foams Using Food Ingredients for Food Packaging Applications
title_fullStr Injection Molded PP Foams Using Food Ingredients for Food Packaging Applications
title_full_unstemmed Injection Molded PP Foams Using Food Ingredients for Food Packaging Applications
title_short Injection Molded PP Foams Using Food Ingredients for Food Packaging Applications
title_sort injection molded pp foams using food ingredients for food packaging applications
topic polypropylene
coating process
foamed PP
foaming agents
food ingredients
url https://www.mdpi.com/2073-4360/13/2/288
work_keys_str_mv AT artemistsagdi injectionmoldedppfoamsusingfoodingredientsforfoodpackagingapplications
AT ioannisdrossos injectionmoldedppfoamsusingfoodingredientsforfoodpackagingapplications
AT despoinageorgiou injectionmoldedppfoamsusingfoodingredientsforfoodpackagingapplications
AT stylianosexarhopoulos injectionmoldedppfoamsusingfoodingredientsforfoodpackagingapplications
AT georgioskarasiotas injectionmoldedppfoamsusingfoodingredientsforfoodpackagingapplications
AT joanniskkallitsis injectionmoldedppfoamsusingfoodingredientsforfoodpackagingapplications
AT elenipkalogianni injectionmoldedppfoamsusingfoodingredientsforfoodpackagingapplications