Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clay

At present, petroleum remains the single largest global source of nearly all transportation fuel and the main source of industrial chemicals. But the legislative demand for cleaner fuel in automobile worldwide has forced scientists to develop and adopt new technologies to reduce the amount of sulphu...

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Main Authors: Abimbola G. Olaremu, Williams R. Adedoyin
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2022-11-01
Series:Materials Reports: Energy
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666935822001094
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author Abimbola G. Olaremu
Williams R. Adedoyin
author_facet Abimbola G. Olaremu
Williams R. Adedoyin
author_sort Abimbola G. Olaremu
collection DOAJ
description At present, petroleum remains the single largest global source of nearly all transportation fuel and the main source of industrial chemicals. But the legislative demand for cleaner fuel in automobile worldwide has forced scientists to develop and adopt new technologies to reduce the amount of sulphur in fuel. In this study, a Co–Mo catalyst supported on zeolite synthesized from local clay was developed and tested in hydrodesulphurization reactions, using Bonny light crude oil feed. The Co–Mo was incorporated into the zeolite by wet impregnation method and its activity was evaluated in a batch reactor. The catalyst was characterized and the efficiency was investigated in terms of product distribution and reaction conditions. With a rise in the temperature, the sulphur in the crude oil gets released into the liquid and gas effluents. In the case of gas effluents, the removal of sulphur depends on the reaction temperature, while in the liquid products, the removal of sulphur lies on the reaction time rather than the reaction temperature. The use of this catalyst results in significant upgraded and enhanced oil production with an environmentally friendly fuel, which therefore recommended as an alternative to conventional industrial catalysts.
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spelling doaj.art-bad8b581597748c7849d0eacb1c901ac2022-12-29T04:14:05ZengKeAi Communications Co. Ltd.Materials Reports: Energy2666-93582022-11-0124100162Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clayAbimbola G. Olaremu0Williams R. Adedoyin1Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria; Centre for Space, Energy and Environmental Research, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria; Corresponding author. Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Ondo State, NigeriaAt present, petroleum remains the single largest global source of nearly all transportation fuel and the main source of industrial chemicals. But the legislative demand for cleaner fuel in automobile worldwide has forced scientists to develop and adopt new technologies to reduce the amount of sulphur in fuel. In this study, a Co–Mo catalyst supported on zeolite synthesized from local clay was developed and tested in hydrodesulphurization reactions, using Bonny light crude oil feed. The Co–Mo was incorporated into the zeolite by wet impregnation method and its activity was evaluated in a batch reactor. The catalyst was characterized and the efficiency was investigated in terms of product distribution and reaction conditions. With a rise in the temperature, the sulphur in the crude oil gets released into the liquid and gas effluents. In the case of gas effluents, the removal of sulphur depends on the reaction temperature, while in the liquid products, the removal of sulphur lies on the reaction time rather than the reaction temperature. The use of this catalyst results in significant upgraded and enhanced oil production with an environmentally friendly fuel, which therefore recommended as an alternative to conventional industrial catalysts.http://www.sciencedirect.com/science/article/pii/S2666935822001094Co-MoBonny lightHydrodesulphurization (HDS)ZeoliteDemetallisationCatalyst
spellingShingle Abimbola G. Olaremu
Williams R. Adedoyin
Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clay
Materials Reports: Energy
Co-Mo
Bonny light
Hydrodesulphurization (HDS)
Zeolite
Demetallisation
Catalyst
title Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clay
title_full Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clay
title_fullStr Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clay
title_full_unstemmed Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clay
title_short Hydrodesulphurization of Bonny light crude oil using nano Co–Mo supported on zeolite synthesized from Akoko clay
title_sort hydrodesulphurization of bonny light crude oil using nano co mo supported on zeolite synthesized from akoko clay
topic Co-Mo
Bonny light
Hydrodesulphurization (HDS)
Zeolite
Demetallisation
Catalyst
url http://www.sciencedirect.com/science/article/pii/S2666935822001094
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AT williamsradedoyin hydrodesulphurizationofbonnylightcrudeoilusingnanocomosupportedonzeolitesynthesizedfromakokoclay