Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperatures

To overcome the slow development of mechanical strengths of sulphoaluminate cement (CSA) in winter construction, this paper investigates the effects of different amounts of admixing Li2CO3 on the setting time, compressive strength, and cooling curve of CSA paste in negative temperatures (−5 °C, −10 ...

Full description

Bibliographic Details
Main Authors: Yanlin Huo, Sile Hu, Dong Lu, Xiaoyu Han, Huayang Sun, Xiaobing Ma, Tianan Liu, Chen Zhang, Zhitao Chen, Jinguang Huang, Yingzi Yang
Format: Article
Language:English
Published: Elsevier 2023-12-01
Series:Case Studies in Construction Materials
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214509523007544
_version_ 1827636235891376128
author Yanlin Huo
Sile Hu
Dong Lu
Xiaoyu Han
Huayang Sun
Xiaobing Ma
Tianan Liu
Chen Zhang
Zhitao Chen
Jinguang Huang
Yingzi Yang
author_facet Yanlin Huo
Sile Hu
Dong Lu
Xiaoyu Han
Huayang Sun
Xiaobing Ma
Tianan Liu
Chen Zhang
Zhitao Chen
Jinguang Huang
Yingzi Yang
author_sort Yanlin Huo
collection DOAJ
description To overcome the slow development of mechanical strengths of sulphoaluminate cement (CSA) in winter construction, this paper investigates the effects of different amounts of admixing Li2CO3 on the setting time, compressive strength, and cooling curve of CSA paste in negative temperatures (−5 °C, −10 °C, and −20 °C). The influence of admixing Li2CO3 on the hydration process and microstructure of CSA paste in a negative temperature environment is also studied using X-ray diffraction (XRD)-Rietveld quantitative analysis, Thermogravimetry (TG) analysis, and Scanning electron microscopy (SEM) observation. The results show that adding Li2CO3 into CSA can significantly improve the mechanical properties at an early age, shorten the curing time, and reduce the freezing point under negative temperatures. The XRD-Rietveld and TG analysis indicates that adding Li2CO3 can increase the consumption of C4A3S̅ and promote the generation of AFt at negative temperatures. It is recommended that the optimum dosage of Li2CO3 should be 0.16 wt% when used as an admixture for CSA systems in negative temperatures.
first_indexed 2024-03-09T15:39:17Z
format Article
id doaj.art-baec2200c09d40c0a43f34470481f86d
institution Directory Open Access Journal
issn 2214-5095
language English
last_indexed 2024-03-09T15:39:17Z
publishDate 2023-12-01
publisher Elsevier
record_format Article
series Case Studies in Construction Materials
spelling doaj.art-baec2200c09d40c0a43f34470481f86d2023-11-25T04:49:21ZengElsevierCase Studies in Construction Materials2214-50952023-12-0119e02574Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperaturesYanlin Huo0Sile Hu1Dong Lu2Xiaoyu Han3Huayang Sun4Xiaobing Ma5Tianan Liu6Chen Zhang7Zhitao Chen8Jinguang Huang9Yingzi Yang10School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, ChinaSchool of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, ChinaSchool of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, China; Corresponding authors at: School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China.School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, ChinaSchool of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, ChinaSchool of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, ChinaInstitute of Engineering Research, Shanghai Construction No 4 Group Co Ltd, Shanghai 200000, ChinaSchool of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, ChinaSchool of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, China; Corresponding authors at: School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China.Zhejiang Construction Engineering Group Co., Ltd., Hangzhou 310012, ChinaSchool of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Structures Dynamic Behavior and Control of the Ministry of Education, Harbin Institute of Technology, Harbin 150090, China; Key Lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology, Harbin Institute of Technology, Harbin 150090, China; Corresponding authors at: School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China.To overcome the slow development of mechanical strengths of sulphoaluminate cement (CSA) in winter construction, this paper investigates the effects of different amounts of admixing Li2CO3 on the setting time, compressive strength, and cooling curve of CSA paste in negative temperatures (−5 °C, −10 °C, and −20 °C). The influence of admixing Li2CO3 on the hydration process and microstructure of CSA paste in a negative temperature environment is also studied using X-ray diffraction (XRD)-Rietveld quantitative analysis, Thermogravimetry (TG) analysis, and Scanning electron microscopy (SEM) observation. The results show that adding Li2CO3 into CSA can significantly improve the mechanical properties at an early age, shorten the curing time, and reduce the freezing point under negative temperatures. The XRD-Rietveld and TG analysis indicates that adding Li2CO3 can increase the consumption of C4A3S̅ and promote the generation of AFt at negative temperatures. It is recommended that the optimum dosage of Li2CO3 should be 0.16 wt% when used as an admixture for CSA systems in negative temperatures.http://www.sciencedirect.com/science/article/pii/S2214509523007544Sulphoaluminate cement (CSA)Li2CO3HydrationMechanical propertiesNegative temperature
spellingShingle Yanlin Huo
Sile Hu
Dong Lu
Xiaoyu Han
Huayang Sun
Xiaobing Ma
Tianan Liu
Chen Zhang
Zhitao Chen
Jinguang Huang
Yingzi Yang
Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperatures
Case Studies in Construction Materials
Sulphoaluminate cement (CSA)
Li2CO3
Hydration
Mechanical properties
Negative temperature
title Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperatures
title_full Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperatures
title_fullStr Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperatures
title_full_unstemmed Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperatures
title_short Understanding the roles of Li2CO3 in a sulphoaluminate cement system at negative temperatures
title_sort understanding the roles of li2co3 in a sulphoaluminate cement system at negative temperatures
topic Sulphoaluminate cement (CSA)
Li2CO3
Hydration
Mechanical properties
Negative temperature
url http://www.sciencedirect.com/science/article/pii/S2214509523007544
work_keys_str_mv AT yanlinhuo understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT silehu understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT donglu understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT xiaoyuhan understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT huayangsun understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT xiaobingma understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT tiananliu understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT chenzhang understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT zhitaochen understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT jinguanghuang understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures
AT yingziyang understandingtherolesofli2co3inasulphoaluminatecementsystematnegativetemperatures