Mechanical and thermal properties of triblock copolymer modified epoxy resins

We investigate the ways of improving thermal and mechanical properties of diglycidyl ether of bisphenol-A (DGEBA) based thermoset resin using diaminodiphenylsulphone (DDS) as hardener and using epoxidized polystyrene/polybutadiene-based triblock copolymers as modifier. The epoxidation was performed...

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Main Authors: Shankar P Khatiwada, Sabu Thomas, Jean Marc Saiter, Ralf Lach, Rameshwar Adhikari
Format: Article
Language:English
Published: Department of Physics, Mahendra Morang Adarsh Multiple Campus, Tribhuvan University 2018-11-01
Series:Bibechana
Subjects:
Online Access:https://www.nepjol.info/index.php/BIBECHANA/article/view/21651
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author Shankar P Khatiwada
Sabu Thomas
Jean Marc Saiter
Ralf Lach
Rameshwar Adhikari
author_facet Shankar P Khatiwada
Sabu Thomas
Jean Marc Saiter
Ralf Lach
Rameshwar Adhikari
author_sort Shankar P Khatiwada
collection DOAJ
description We investigate the ways of improving thermal and mechanical properties of diglycidyl ether of bisphenol-A (DGEBA) based thermoset resin using diaminodiphenylsulphone (DDS) as hardener and using epoxidized polystyrene/polybutadiene-based triblock copolymers as modifier. The epoxidation was performed. The targeted chemical modification using meta-chloroperoxybenzoic acid (m-CPBA) of the copolymer was performed whereby the epoxidation of the butadiene chains mainly took place at 1,4 linkages. The modification copolymer was found to contribute in enhancing the mechanical performance of the blends with epoxy resin. The results indicated the formation of nanostructured morphology in the blends attributable to their enhanced impact strength. BIBECHANA 16 (2019) 196-203
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spelling doaj.art-bb0bc82a6b5b4afb84be0f60d859b7c72024-04-23T13:05:16ZengDepartment of Physics, Mahendra Morang Adarsh Multiple Campus, Tribhuvan UniversityBibechana2091-07622382-53402018-11-011610.3126/bibechana.v16i0.2165119327Mechanical and thermal properties of triblock copolymer modified epoxy resinsShankar P Khatiwada0Sabu Thomas1Jean Marc Saiter2Ralf Lach3Rameshwar Adhikari4Research Center for Applied Science and Technology, Tribhuvan University, Kirtipur, KathmanduSchool of Chemical Sciences, Mahatma Gandhi University, Kottayam, KeralaUniversité de Normandie Rouen Laboratoire SMS Faculté des Sciences and Onyx Developpment, Groupe-Nutriset, RouenPolymer Service GmbH Merseburg (PSM), Merseburg,Central Department of Chemistry, Tribhuvan University, Kirtipur, Katmandu We investigate the ways of improving thermal and mechanical properties of diglycidyl ether of bisphenol-A (DGEBA) based thermoset resin using diaminodiphenylsulphone (DDS) as hardener and using epoxidized polystyrene/polybutadiene-based triblock copolymers as modifier. The epoxidation was performed. The targeted chemical modification using meta-chloroperoxybenzoic acid (m-CPBA) of the copolymer was performed whereby the epoxidation of the butadiene chains mainly took place at 1,4 linkages. The modification copolymer was found to contribute in enhancing the mechanical performance of the blends with epoxy resin. The results indicated the formation of nanostructured morphology in the blends attributable to their enhanced impact strength. BIBECHANA 16 (2019) 196-203 https://www.nepjol.info/index.php/BIBECHANA/article/view/21651Block copolymersEpoxy resinsToughnessMechanical properties
spellingShingle Shankar P Khatiwada
Sabu Thomas
Jean Marc Saiter
Ralf Lach
Rameshwar Adhikari
Mechanical and thermal properties of triblock copolymer modified epoxy resins
Bibechana
Block copolymers
Epoxy resins
Toughness
Mechanical properties
title Mechanical and thermal properties of triblock copolymer modified epoxy resins
title_full Mechanical and thermal properties of triblock copolymer modified epoxy resins
title_fullStr Mechanical and thermal properties of triblock copolymer modified epoxy resins
title_full_unstemmed Mechanical and thermal properties of triblock copolymer modified epoxy resins
title_short Mechanical and thermal properties of triblock copolymer modified epoxy resins
title_sort mechanical and thermal properties of triblock copolymer modified epoxy resins
topic Block copolymers
Epoxy resins
Toughness
Mechanical properties
url https://www.nepjol.info/index.php/BIBECHANA/article/view/21651
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AT sabuthomas mechanicalandthermalpropertiesoftriblockcopolymermodifiedepoxyresins
AT jeanmarcsaiter mechanicalandthermalpropertiesoftriblockcopolymermodifiedepoxyresins
AT ralflach mechanicalandthermalpropertiesoftriblockcopolymermodifiedepoxyresins
AT rameshwaradhikari mechanicalandthermalpropertiesoftriblockcopolymermodifiedepoxyresins