Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)]
The dinuclear molecule of the title complex, [VOCl{μ-OC(Me)2P(iPr)2-κ2O}]2 or [V2(C9H20O2P)2Cl2O2], which was obtained due to an unexpected oxidation reaction, is centrosymmetric, with the inversion centre located in the middle of the central V2O2 core. These core O atoms arise from the symmetry-rel...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016007362 |
| _version_ | 1819294807170744320 |
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| author | Mathias Glatz Berthold Stöger Matthias Weil Karl Kirchner |
| author_facet | Mathias Glatz Berthold Stöger Matthias Weil Karl Kirchner |
| author_sort | Mathias Glatz |
| collection | DOAJ |
| description | The dinuclear molecule of the title complex, [VOCl{μ-OC(Me)2P(iPr)2-κ2O}]2 or [V2(C9H20O2P)2Cl2O2], which was obtained due to an unexpected oxidation reaction, is centrosymmetric, with the inversion centre located in the middle of the central V2O2 core. These core O atoms arise from the symmetry-related 2-(diisopropylphosphoryl)propan-2-olate dianions. The VIV atom is additionally bonded to one terminal Cl ligand, the second O atom of the dianion and double bonded to a vanadyl O atom, leading to an overall distorted square-pyramidal VO4Cl coordination polyhedron with the vanadyl O atom as the apex. An intramolecular C—H...Cl contact helps to establish the molecular configuration. In the crystal, molecules are stacked in rows parallel to [001] and are linked by C—H...Cl contacts to form chains running in the same direction. |
| first_indexed | 2024-12-24T04:32:11Z |
| format | Article |
| id | doaj.art-bb0e34caade3431eb041f67fd5fca12d |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-24T04:32:11Z |
| publishDate | 2016-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-bb0e34caade3431eb041f67fd5fca12d2022-12-21T17:15:22ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-06-0172678578810.1107/S2056989016007362hb7583Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)]Mathias Glatz0Berthold Stöger1Matthias Weil2Karl Kirchner3Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-OC, 1060 Vienna, AustriaInstitute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, AustriaInstitute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, AustriaInstitute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-OC, 1060 Vienna, AustriaThe dinuclear molecule of the title complex, [VOCl{μ-OC(Me)2P(iPr)2-κ2O}]2 or [V2(C9H20O2P)2Cl2O2], which was obtained due to an unexpected oxidation reaction, is centrosymmetric, with the inversion centre located in the middle of the central V2O2 core. These core O atoms arise from the symmetry-related 2-(diisopropylphosphoryl)propan-2-olate dianions. The VIV atom is additionally bonded to one terminal Cl ligand, the second O atom of the dianion and double bonded to a vanadyl O atom, leading to an overall distorted square-pyramidal VO4Cl coordination polyhedron with the vanadyl O atom as the apex. An intramolecular C—H...Cl contact helps to establish the molecular configuration. In the crystal, molecules are stacked in rows parallel to [001] and are linked by C—H...Cl contacts to form chains running in the same direction.http://scripts.iucr.org/cgi-bin/paper?S2056989016007362crystal structurebinuclear centrosymmetric complexvanadiumsquare-pyramidal coordination geometry |
| spellingShingle | Mathias Glatz Berthold Stöger Matthias Weil Karl Kirchner Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)] Acta Crystallographica Section E: Crystallographic Communications crystal structure binuclear centrosymmetric complex vanadium square-pyramidal coordination geometry |
| title | Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)] |
| title_full | Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)] |
| title_fullStr | Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)] |
| title_full_unstemmed | Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)] |
| title_short | Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)] |
| title_sort | crystal structure of bis μ 2 diisopropylphosphoryl propan 2 olato κ3o1 o2 o1 bis chloridooxidovanadium iv |
| topic | crystal structure binuclear centrosymmetric complex vanadium square-pyramidal coordination geometry |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016007362 |
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