Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)]

Crystal structure of bis[μ-2-(diisopropylphosphoryl)propan-2-olato-κ3O1,O2:O1]bis[chloridooxidovanadium(IV)]

The dinuclear molecule of the title complex, [VOCl{μ-OC(Me)2P(iPr)2-κ2O}]2 or [V2(C9H20O2P)2Cl2O2], which was obtained due to an unexpected oxidation reaction, is centrosymmetric, with the inversion centre located in the middle of the central V2O2 core. These core O atoms arise from the symmetry-rel...

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Bibliographic Details
Main Authors:	Mathias Glatz, Berthold Stöger, Matthias Weil, Karl Kirchner
Format:	Article
Language:	English
Published:	International Union of Crystallography 2016-06-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure binuclear centrosymmetric complex vanadium square-pyramidal coordination geometry
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989016007362

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