Mechanical properties and modification mechanism of phosphogypsum stabilized soil

Abstract The red clay is widely distributed in Guizhou province, which is characterized by high natural moisture content, difficult compaction and serious shrinkage and crackingin, and phosphogypsum is discharged for 5 million tons every year in Guizhou province. For the sake of effectively reducing...

Full description

Bibliographic Details
Main Authors: Bolang Zhang, Kaisheng Chen, Kun Zhang, Dipu Luo
Format: Article
Language:English
Published: Springer 2022-07-01
Series:SN Applied Sciences
Subjects:
Online Access:https://doi.org/10.1007/s42452-022-05124-7
_version_ 1818163021941309440
author Bolang Zhang
Kaisheng Chen
Kun Zhang
Dipu Luo
author_facet Bolang Zhang
Kaisheng Chen
Kun Zhang
Dipu Luo
author_sort Bolang Zhang
collection DOAJ
description Abstract The red clay is widely distributed in Guizhou province, which is characterized by high natural moisture content, difficult compaction and serious shrinkage and crackingin, and phosphogypsum is discharged for 5 million tons every year in Guizhou province. For the sake of effectively reducing the accumulation of phosphogypsum, mixtures were prepared with cement as a curing agent and mass ratios of cement to phosphogypsum of 1:1, 1:2 and 1:3 (low content phosphogypsum group) and phosphogypsum to red clay of 1:1, 1:2 and 1:3 (high content phosphogypsum group). Unconfined compressive strength, expansion, shrinkage and dynamic characteristic tests were conducted to analyze the behavior and mechanical properties of the mixtures. The modification mechanism of the mixtures by phosphogypsum was further explored by XRD (X-ray diffraction) and SEM (scanning electron microscopy). which provided a theoretical basis for the application of phosphogypsum in highway engineering and improved the engineering properties of red clay. The results show that the unconfined compressive strength of the phosphogypsum stabilized soil in the low content phosphogypsum group is greater than that in the high content phosphogypsum group. When cement:phosphogypsum = 1:2.2–1:3, the unconfined compressive strength of the mixture is maximum. When cement:phosphogypsum = 1:3, the maximum dynamic shear modulus of phosphogypsum stabilized soil is the largest. The absolute expansion rate and linear shrinkage rate of phosphogypsum stabilized soil in the low content phosphogypsum group are greater than those in the high content phosphogypsum group. When cement: phosphogypsum = 1:1–1:3, the absolute expansion rate is 6.5–12.3%, and the linear shrinkage rate is 1.3–2%. When red clay:Phosphogypsum = 1:1–1:3, the absolute expansion rate is 0.2–4%, and the linear shrinkage rate is 1–1.5%. The more phosphogypsum content, the smaller the expansion deformation and shrinkage deformation of the mixture. It is suggested that mass ratios of phosphogypsum to red clay is 1:1, and the cement content is 5%. Which can not only make full use of phosphogypsum solid waste, but also improve the engineering properties of red clay. Article Highlights The unconfined compressive strength of the phosphogypsum stabilized soil in the low content phosphogypsum group is greater than that in the high content phosphogypsum group. The absolute expansion rate and linear shrinkage rate of phosphogypsum stabilized soil in the low content phosphogypsum group are greater than those in the high content phosphogypsum group. The strength of phosphogypsum stabilized soil is derived from the comprehensive effect of cement and phosphogypsum. Due to the increment of the phosphogypsum and the decline of proportion of red clay, leading to the decrease in the content of hydrophilic minerals, the expansion deformation and shrinkage deformation characteristics are changed. Considering strength and deformation characteristics, it is recommended that mixtures with 5% cement content, and phosphogypsum to red clay of 1:1 as subgrade filler, which can not only make full use of phosphogypsum solid waste, but also improve the engineering properties of red clay.
first_indexed 2024-12-11T16:42:57Z
format Article
id doaj.art-bb1e2184b2444432b1155655f9c7ee2e
institution Directory Open Access Journal
issn 2523-3963
2523-3971
language English
last_indexed 2024-12-11T16:42:57Z
publishDate 2022-07-01
publisher Springer
record_format Article
series SN Applied Sciences
spelling doaj.art-bb1e2184b2444432b1155655f9c7ee2e2022-12-22T00:58:16ZengSpringerSN Applied Sciences2523-39632523-39712022-07-014811910.1007/s42452-022-05124-7Mechanical properties and modification mechanism of phosphogypsum stabilized soilBolang Zhang0Kaisheng Chen1Kun Zhang2Dipu Luo3School of Civil Engineering, Guizhou UniversitySchool of Civil Engineering, Guizhou UniversitySchool of Civil Engineering, Guizhou UniversitySchool of Civil Engineering, Guizhou UniversityAbstract The red clay is widely distributed in Guizhou province, which is characterized by high natural moisture content, difficult compaction and serious shrinkage and crackingin, and phosphogypsum is discharged for 5 million tons every year in Guizhou province. For the sake of effectively reducing the accumulation of phosphogypsum, mixtures were prepared with cement as a curing agent and mass ratios of cement to phosphogypsum of 1:1, 1:2 and 1:3 (low content phosphogypsum group) and phosphogypsum to red clay of 1:1, 1:2 and 1:3 (high content phosphogypsum group). Unconfined compressive strength, expansion, shrinkage and dynamic characteristic tests were conducted to analyze the behavior and mechanical properties of the mixtures. The modification mechanism of the mixtures by phosphogypsum was further explored by XRD (X-ray diffraction) and SEM (scanning electron microscopy). which provided a theoretical basis for the application of phosphogypsum in highway engineering and improved the engineering properties of red clay. The results show that the unconfined compressive strength of the phosphogypsum stabilized soil in the low content phosphogypsum group is greater than that in the high content phosphogypsum group. When cement:phosphogypsum = 1:2.2–1:3, the unconfined compressive strength of the mixture is maximum. When cement:phosphogypsum = 1:3, the maximum dynamic shear modulus of phosphogypsum stabilized soil is the largest. The absolute expansion rate and linear shrinkage rate of phosphogypsum stabilized soil in the low content phosphogypsum group are greater than those in the high content phosphogypsum group. When cement: phosphogypsum = 1:1–1:3, the absolute expansion rate is 6.5–12.3%, and the linear shrinkage rate is 1.3–2%. When red clay:Phosphogypsum = 1:1–1:3, the absolute expansion rate is 0.2–4%, and the linear shrinkage rate is 1–1.5%. The more phosphogypsum content, the smaller the expansion deformation and shrinkage deformation of the mixture. It is suggested that mass ratios of phosphogypsum to red clay is 1:1, and the cement content is 5%. Which can not only make full use of phosphogypsum solid waste, but also improve the engineering properties of red clay. Article Highlights The unconfined compressive strength of the phosphogypsum stabilized soil in the low content phosphogypsum group is greater than that in the high content phosphogypsum group. The absolute expansion rate and linear shrinkage rate of phosphogypsum stabilized soil in the low content phosphogypsum group are greater than those in the high content phosphogypsum group. The strength of phosphogypsum stabilized soil is derived from the comprehensive effect of cement and phosphogypsum. Due to the increment of the phosphogypsum and the decline of proportion of red clay, leading to the decrease in the content of hydrophilic minerals, the expansion deformation and shrinkage deformation characteristics are changed. Considering strength and deformation characteristics, it is recommended that mixtures with 5% cement content, and phosphogypsum to red clay of 1:1 as subgrade filler, which can not only make full use of phosphogypsum solid waste, but also improve the engineering properties of red clay.https://doi.org/10.1007/s42452-022-05124-7CementPhosphogypsumRed clayMechanical propertiesModification mechanism
spellingShingle Bolang Zhang
Kaisheng Chen
Kun Zhang
Dipu Luo
Mechanical properties and modification mechanism of phosphogypsum stabilized soil
SN Applied Sciences
Cement
Phosphogypsum
Red clay
Mechanical properties
Modification mechanism
title Mechanical properties and modification mechanism of phosphogypsum stabilized soil
title_full Mechanical properties and modification mechanism of phosphogypsum stabilized soil
title_fullStr Mechanical properties and modification mechanism of phosphogypsum stabilized soil
title_full_unstemmed Mechanical properties and modification mechanism of phosphogypsum stabilized soil
title_short Mechanical properties and modification mechanism of phosphogypsum stabilized soil
title_sort mechanical properties and modification mechanism of phosphogypsum stabilized soil
topic Cement
Phosphogypsum
Red clay
Mechanical properties
Modification mechanism
url https://doi.org/10.1007/s42452-022-05124-7
work_keys_str_mv AT bolangzhang mechanicalpropertiesandmodificationmechanismofphosphogypsumstabilizedsoil
AT kaishengchen mechanicalpropertiesandmodificationmechanismofphosphogypsumstabilizedsoil
AT kunzhang mechanicalpropertiesandmodificationmechanismofphosphogypsumstabilizedsoil
AT dipuluo mechanicalpropertiesandmodificationmechanismofphosphogypsumstabilizedsoil