Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrate
In the title compound [Fe(NCS)2(C8H6N4S)2(H2O)2]·H2O, the FeII cation is coordinated by two N-bonded thiocyanate anions, two N4-bonded bis(pyrazin-2-yl) sulfide ligands and two water molecules in an slightly distorted octahedral geometry. The FeII cation is located on a center of inversion...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813006314 |
| _version_ | 1819290564932141056 |
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| author | Susanne Wöhlert Inke Jess Christian Näther |
| author_facet | Susanne Wöhlert Inke Jess Christian Näther |
| author_sort | Susanne Wöhlert |
| collection | DOAJ |
| description | In the title compound [Fe(NCS)2(C8H6N4S)2(H2O)2]·H2O, the FeII cation is coordinated by two N-bonded thiocyanate anions, two N4-bonded bis(pyrazin-2-yl) sulfide ligands and two water molecules in an slightly distorted octahedral geometry. The FeII cation is located on a center of inversion and the lattice water molecule on a twofold rotation axis. The thiocyanate anions, the coordinating water molecules and the sulfide ligands occupy general positions. The complex molecules and lattice water molecules are linked into a three-dimensional network by O—H—N and O—H...O hydrogen bonds. |
| first_indexed | 2024-12-24T03:24:45Z |
| format | Article |
| id | doaj.art-bb209e0d057d45abbaf9f3dccdecce9c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:24:45Z |
| publishDate | 2013-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-bb209e0d057d45abbaf9f3dccdecce9c2022-12-21T17:17:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694m196m19610.1107/S1600536813006314Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrateSusanne WöhlertInke JessChristian NätherIn the title compound [Fe(NCS)2(C8H6N4S)2(H2O)2]·H2O, the FeII cation is coordinated by two N-bonded thiocyanate anions, two N4-bonded bis(pyrazin-2-yl) sulfide ligands and two water molecules in an slightly distorted octahedral geometry. The FeII cation is located on a center of inversion and the lattice water molecule on a twofold rotation axis. The thiocyanate anions, the coordinating water molecules and the sulfide ligands occupy general positions. The complex molecules and lattice water molecules are linked into a three-dimensional network by O—H—N and O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536813006314 |
| spellingShingle | Susanne Wöhlert Inke Jess Christian Näther Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrate Acta Crystallographica Section E |
| title | Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrate |
| title_full | Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrate |
| title_fullStr | Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrate |
| title_full_unstemmed | Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrate |
| title_short | Diaquabis[bis(pyrazin-2-yl) sulfide-κN4]bis(thiocyanato-κN)iron(II) monohydrate |
| title_sort | diaquabis bis pyrazin 2 yl sulfide 954 n4 bis thiocyanato 954 n iron ii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813006314 |
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