Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers

There is a possibility of obtaining xylitol-based elastomers sharing common characteristics of biodegradability, thermal stability, and elastomeric behavior by using monomers with different chain-lengths. Therefore, we have synthesized eight elastomers using a combination of four different diols (et...

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Bibliographic Details
Main Authors: Marta Piątek-Hnat, Kuba Bomba, Janusz P. Kowalski-Stankiewicz, Jakub Pęksiński, Agnieszka Kozłowska, Jacek G. Sośnicki, Tomasz J. Idzik, Beata Schmidt, Krzysztof Kowalczyk, Marta Walo, Agnieszka Kochmańska
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/7/1041
Description
Summary:There is a possibility of obtaining xylitol-based elastomers sharing common characteristics of biodegradability, thermal stability, and elastomeric behavior by using monomers with different chain-lengths. Therefore, we have synthesized eight elastomers using a combination of four different diols (ethanediol, 1.3-propanediol, 1.4-buanediol, and 1.5-pentanediol) and two different dicarboxylic acids (succinic acid and adipic acid). The obtained materials were further modified by performing e-beam treatment with a dose of 100 kGy. Materials both before and after radiation modification were tested by DSC, DMTA, TGA, tensile tests, gel fraction determination, hydrolytic and enzymatic degradation tests, <sup>1</sup>H NMR and <sup>13</sup>C NMR and FTIR.
ISSN:2073-4360