Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers
There is a possibility of obtaining xylitol-based elastomers sharing common characteristics of biodegradability, thermal stability, and elastomeric behavior by using monomers with different chain-lengths. Therefore, we have synthesized eight elastomers using a combination of four different diols (et...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-03-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/13/7/1041 |
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| author | Marta Piątek-Hnat Kuba Bomba Janusz P. Kowalski-Stankiewicz Jakub Pęksiński Agnieszka Kozłowska Jacek G. Sośnicki Tomasz J. Idzik Beata Schmidt Krzysztof Kowalczyk Marta Walo Agnieszka Kochmańska |
| author_facet | Marta Piątek-Hnat Kuba Bomba Janusz P. Kowalski-Stankiewicz Jakub Pęksiński Agnieszka Kozłowska Jacek G. Sośnicki Tomasz J. Idzik Beata Schmidt Krzysztof Kowalczyk Marta Walo Agnieszka Kochmańska |
| author_sort | Marta Piątek-Hnat |
| collection | DOAJ |
| description | There is a possibility of obtaining xylitol-based elastomers sharing common characteristics of biodegradability, thermal stability, and elastomeric behavior by using monomers with different chain-lengths. Therefore, we have synthesized eight elastomers using a combination of four different diols (ethanediol, 1.3-propanediol, 1.4-buanediol, and 1.5-pentanediol) and two different dicarboxylic acids (succinic acid and adipic acid). The obtained materials were further modified by performing e-beam treatment with a dose of 100 kGy. Materials both before and after radiation modification were tested by DSC, DMTA, TGA, tensile tests, gel fraction determination, hydrolytic and enzymatic degradation tests, <sup>1</sup>H NMR and <sup>13</sup>C NMR and FTIR. |
| first_indexed | 2024-03-10T12:52:31Z |
| format | Article |
| id | doaj.art-bb56bc74161e4b2fb9bedb46cc72b2bb |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-10T12:52:31Z |
| publishDate | 2021-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-bb56bc74161e4b2fb9bedb46cc72b2bb2023-11-21T12:11:25ZengMDPI AGPolymers2073-43602021-03-01137104110.3390/polym13071041Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different MonomersMarta Piątek-Hnat0Kuba Bomba1Janusz P. Kowalski-Stankiewicz2Jakub Pęksiński3Agnieszka Kozłowska4Jacek G. Sośnicki5Tomasz J. Idzik6Beata Schmidt7Krzysztof Kowalczyk8Marta Walo9Agnieszka Kochmańska10Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, 71-065 Szczecin, PolandFaculty of Chemical Technology and Engineering, West Pomeranian University of Technology, 71-065 Szczecin, PolandDepartment of Computer Sciences in Medicine & Education Quality Evaluation, Pomeranian Medical University in Szczecin, 70-204 Szczecin, PolandFaculty of Electrical Engineering, West Pomeranian University of Technology, 71-313 Szczecin, PolandFaculty of Chemical Technology and Engineering, West Pomeranian University of Technology, 71-065 Szczecin, PolandDepartment of Organic and Physical Chemistry, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, 71-065 Szczecin, PolandDepartment of Organic and Physical Chemistry, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, 71-065 Szczecin, PolandDepartment of Chemical Organic Technology and Polymeric Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, 71-065 Szczecin, PolandDepartment of Chemical Organic Technology and Polymeric Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, 71-065 Szczecin, PolandLaboratory for Measurements of Technological Doses, Institute of Nuclear Chemistry and Technology, 03-195 Warszawa, PolandDepartment of Materials Technology, West Pomeranian University of Technology, 70-310 Szczecin, PolandThere is a possibility of obtaining xylitol-based elastomers sharing common characteristics of biodegradability, thermal stability, and elastomeric behavior by using monomers with different chain-lengths. Therefore, we have synthesized eight elastomers using a combination of four different diols (ethanediol, 1.3-propanediol, 1.4-buanediol, and 1.5-pentanediol) and two different dicarboxylic acids (succinic acid and adipic acid). The obtained materials were further modified by performing e-beam treatment with a dose of 100 kGy. Materials both before and after radiation modification were tested by DSC, DMTA, TGA, tensile tests, gel fraction determination, hydrolytic and enzymatic degradation tests, <sup>1</sup>H NMR and <sup>13</sup>C NMR and FTIR.https://www.mdpi.com/2073-4360/13/7/1041radiation modificatione-beamxylitolbiodegradable elastomersmechanical and thermal properties |
| spellingShingle | Marta Piątek-Hnat Kuba Bomba Janusz P. Kowalski-Stankiewicz Jakub Pęksiński Agnieszka Kozłowska Jacek G. Sośnicki Tomasz J. Idzik Beata Schmidt Krzysztof Kowalczyk Marta Walo Agnieszka Kochmańska Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers Polymers radiation modification e-beam xylitol biodegradable elastomers mechanical and thermal properties |
| title | Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers |
| title_full | Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers |
| title_fullStr | Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers |
| title_full_unstemmed | Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers |
| title_short | Physical Effects of Radiation Modification of Biodegradable Xylitol-Based Materials Synthesized Using a Combination of Different Monomers |
| title_sort | physical effects of radiation modification of biodegradable xylitol based materials synthesized using a combination of different monomers |
| topic | radiation modification e-beam xylitol biodegradable elastomers mechanical and thermal properties |
| url | https://www.mdpi.com/2073-4360/13/7/1041 |
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