Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
Despite the burgeoning nature of uranium–ligand multiple bonding, analogous thorium complexes remain incredibly rare. Here the authors report evidence for a transient thorium–nitride species, which, together with data on parent imido derivatives, suggests that the pushing-from-below phenomenon may b...
Main Authors: | Jingzhen Du, Carlos Alvarez-Lamsfus, Elizabeth P. Wildman, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle |
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Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2019-09-01
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Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-019-12206-5 |
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