Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)]
The title compound, [Na3(C14H14N3O3S)3(C4H8O2)3]n, is a polynuclear complex which includes, in the monomeric unit, three units of NaI-4′-dimethylaminoazobenzene-4-sulfonate [known as methyl orange (MO)] and three molecules of dioxane (C4H8O2). These constitute three kinds of NaI centres, t...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-04-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808008015 |
| _version_ | 1819290676597096448 |
|---|---|
| author | Jin Mizuguchi Hiroki Shibata Kazuyuki Sato |
| author_facet | Jin Mizuguchi Hiroki Shibata Kazuyuki Sato |
| author_sort | Jin Mizuguchi |
| collection | DOAJ |
| description | The title compound, [Na3(C14H14N3O3S)3(C4H8O2)3]n, is a polynuclear complex which includes, in the monomeric unit, three units of NaI-4′-dimethylaminoazobenzene-4-sulfonate [known as methyl orange (MO)] and three molecules of dioxane (C4H8O2). These constitute three kinds of NaI centres, two of which are seven-coordinate while the third is five-coordinate. One of the seven-coordinate centres is coordinated by six O atoms from the sulfonate groups of four different MOs and by one O atom from dioxane. The other is coordinated by seven O atoms from the sulfonate groups of five different MOs. The five-coordinate centre is coordinated by three O atoms from the sulfonate groups of three different MOs and two O atoms from two different dioxanes. In the crystal structure, a one-dimensional polymer chain is formed along the a axis and this ensures the thermal stability of the title compound. It is also to be noted that the N=N bond lengths of the three azo groups are appreciably different [1.259 (4), 1.196 (4), and 1.253 (4) Å]. |
| first_indexed | 2024-12-24T03:26:32Z |
| format | Article |
| id | doaj.art-bb8db1e8a05a42d481bda960c3915a1b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:26:32Z |
| publishDate | 2008-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-bb8db1e8a05a42d481bda960c3915a1b2022-12-21T17:17:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-04-01644m586m58710.1107/S1600536808008015Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)]Jin MizuguchiHiroki ShibataKazuyuki SatoThe title compound, [Na3(C14H14N3O3S)3(C4H8O2)3]n, is a polynuclear complex which includes, in the monomeric unit, three units of NaI-4′-dimethylaminoazobenzene-4-sulfonate [known as methyl orange (MO)] and three molecules of dioxane (C4H8O2). These constitute three kinds of NaI centres, two of which are seven-coordinate while the third is five-coordinate. One of the seven-coordinate centres is coordinated by six O atoms from the sulfonate groups of four different MOs and by one O atom from dioxane. The other is coordinated by seven O atoms from the sulfonate groups of five different MOs. The five-coordinate centre is coordinated by three O atoms from the sulfonate groups of three different MOs and two O atoms from two different dioxanes. In the crystal structure, a one-dimensional polymer chain is formed along the a axis and this ensures the thermal stability of the title compound. It is also to be noted that the N=N bond lengths of the three azo groups are appreciably different [1.259 (4), 1.196 (4), and 1.253 (4) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536808008015 |
| spellingShingle | Jin Mizuguchi Hiroki Shibata Kazuyuki Sato Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)] Acta Crystallographica Section E |
| title | Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)] |
| title_full | Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)] |
| title_fullStr | Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)] |
| title_full_unstemmed | Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)] |
| title_short | Poly[tris{μ2-4-[4-(dimethylamino)phenyldiazenyl]benzenesulfonato}tridioxanetrisodium(I)] |
| title_sort | poly tris 956 2 4 4 dimethylamino phenyldiazenyl benzenesulfonato tridioxanetrisodium i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808008015 |
| work_keys_str_mv | AT jinmizuguchi polytris956244dimethylaminophenyldiazenylbenzenesulfonatotridioxanetrisodiumi AT hirokishibata polytris956244dimethylaminophenyldiazenylbenzenesulfonatotridioxanetrisodiumi AT kazuyukisato polytris956244dimethylaminophenyldiazenylbenzenesulfonatotridioxanetrisodiumi |