Magnesium substitution in calcium and strontium fluoro-phospho-aluminosilicate glasses by multinuclear 19F, 31P, 27Al, and 29Si MAS-NMR spectroscopy

Two series of glasses were produced by systematically substituting magnesium for calcium and strontium in the glass compositions, 4.5SiO2. 3Al2O3. 1.5P2O5. (3-x)CaO/SrO. xMgO. (2-y)CaF2/SrF2. yMgF2, 0 ≥ x ≥ 3, 0 ≥ y ≥ 2 and these glasses were characterised by 19F, 31P, 27Al, and 29Si MAS-NMR spectro...

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Bibliographic Details
Main Authors: Hiroko Kusumoto, Robert G. Hill, Natalia Karpukhina, Robert V. Law
Format: Article
Language:English
Published: Elsevier 2019-03-01
Series:Journal of Non-Crystalline Solids: X
Online Access:http://www.sciencedirect.com/science/article/pii/S2590159119300214