Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric Acid

X-ray computer tomography (XRT) is a three-dimensional, nondestructive, and thus reproducible examination method that allows for the investigation of internal and external structures of objects. Due to its characteristics, the XRT technique has increasingly established itself as an alternative exami...

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Main Authors: Anita Razavi, Alena Stein, Peter Quirmbach
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/7/884
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author Anita Razavi
Alena Stein
Peter Quirmbach
author_facet Anita Razavi
Alena Stein
Peter Quirmbach
author_sort Anita Razavi
collection DOAJ
description X-ray computer tomography (XRT) is a three-dimensional, nondestructive, and thus reproducible examination method that allows for the investigation of internal and external structures of objects. Due to its characteristics, the XRT technique has increasingly established itself as an alternative examination method and is also applied in the field of mineral processing. Within this work, XRT is used to investigate the influence of hydrochloric acid leaching of iron-rich bauxites on grain composition. Acid leaching is a promising method for the beneficiation of iron-rich bauxites for refractories. Many studies have already established that leaching with hydrochloric acid can reduce the Fe<sub>2</sub>O<sub>3</sub> content in bauxites. However, apart from the influence of the leaching process on the composition of the bauxites, aspects such as the influence of the acid on the exact grain constitution or the porosity behavior have rarely been considered so far. To address these open questions, XRT analysis was used to examine and characterize various bauxites. By comparing identical grains before and after leaching, it was observed that in gibbsite bauxites the acid penetration is deeper, and the volume decreases significantly. In diasporic and boehmitic bauxites, clear leaching edges can be seen in which the iron content has been reduced.
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spelling doaj.art-bbd11a65f15d47e8b4d01307923aec832023-11-18T20:38:21ZengMDPI AGMinerals2075-163X2023-06-0113788410.3390/min13070884Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric AcidAnita Razavi0Alena Stein1Peter Quirmbach2Institute for Natural Sciences—Technical Chemistry and Corrosion Sciences, University of Koblenz, Universitaetsstr. 1, 56070 Koblenz, GermanyInstitute for Natural Sciences—Technical Chemistry and Corrosion Sciences, University of Koblenz, Universitaetsstr. 1, 56070 Koblenz, GermanyInstitute for Natural Sciences—Technical Chemistry and Corrosion Sciences, University of Koblenz, Universitaetsstr. 1, 56070 Koblenz, GermanyX-ray computer tomography (XRT) is a three-dimensional, nondestructive, and thus reproducible examination method that allows for the investigation of internal and external structures of objects. Due to its characteristics, the XRT technique has increasingly established itself as an alternative examination method and is also applied in the field of mineral processing. Within this work, XRT is used to investigate the influence of hydrochloric acid leaching of iron-rich bauxites on grain composition. Acid leaching is a promising method for the beneficiation of iron-rich bauxites for refractories. Many studies have already established that leaching with hydrochloric acid can reduce the Fe<sub>2</sub>O<sub>3</sub> content in bauxites. However, apart from the influence of the leaching process on the composition of the bauxites, aspects such as the influence of the acid on the exact grain constitution or the porosity behavior have rarely been considered so far. To address these open questions, XRT analysis was used to examine and characterize various bauxites. By comparing identical grains before and after leaching, it was observed that in gibbsite bauxites the acid penetration is deeper, and the volume decreases significantly. In diasporic and boehmitic bauxites, clear leaching edges can be seen in which the iron content has been reduced.https://www.mdpi.com/2075-163X/13/7/884X-ray computer tomography (XRT)bauxiterefractory gradeiron removalacid leaching
spellingShingle Anita Razavi
Alena Stein
Peter Quirmbach
Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric Acid
Minerals
X-ray computer tomography (XRT)
bauxite
refractory grade
iron removal
acid leaching
title Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric Acid
title_full Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric Acid
title_fullStr Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric Acid
title_full_unstemmed Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric Acid
title_short Tomographic Imaging of Bauxite Grains Leached Using Hydrochloric Acid
title_sort tomographic imaging of bauxite grains leached using hydrochloric acid
topic X-ray computer tomography (XRT)
bauxite
refractory grade
iron removal
acid leaching
url https://www.mdpi.com/2075-163X/13/7/884
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