Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystal

Analytical expressions are obtained for g-factors of the ground Kramers doublet of the impurity Ce<sup>3+</sup> ions in LiYF<sub>4</sub> crystal that rigorously take into account mixing of the <sup>2</sup>F<sub>5/2</sub> and <sup>2</sup>F&l...

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Main Author: O.V. Solovyev
Format: Article
Language:English
Published: Kazan Federal University 2015-12-01
Series:Magnetic Resonance in Solids
Subjects:
Online Access:http://mrsej.kpfu.ru/contents/2015/MRSej_15103.pdf
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author O.V. Solovyev
author_facet O.V. Solovyev
author_sort O.V. Solovyev
collection DOAJ
description Analytical expressions are obtained for g-factors of the ground Kramers doublet of the impurity Ce<sup>3+</sup> ions in LiYF<sub>4</sub> crystal that rigorously take into account mixing of the <sup>2</sup>F<sub>5/2</sub> and <sup>2</sup>F<sub>7/2</sub> multiplets by crystal field. Dependence of g-factors on crystal field parameters is studied and possibilities of making conclusions about crystal filed parameters values on the basis of comparison with g-factors given in literature are considered.
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spelling doaj.art-bbd1943aec544a6db5cfc1f2756209742022-12-21T19:44:28ZengKazan Federal UniversityMagnetic Resonance in Solids2072-59812015-12-0117115103Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystalO.V. Solovyev0Kazan Federal University, Kremlevskaya 18, Kazan 420008, RussiaAnalytical expressions are obtained for g-factors of the ground Kramers doublet of the impurity Ce<sup>3+</sup> ions in LiYF<sub>4</sub> crystal that rigorously take into account mixing of the <sup>2</sup>F<sub>5/2</sub> and <sup>2</sup>F<sub>7/2</sub> multiplets by crystal field. Dependence of g-factors on crystal field parameters is studied and possibilities of making conclusions about crystal filed parameters values on the basis of comparison with g-factors given in literature are considered.http://mrsej.kpfu.ru/contents/2015/MRSej_15103.pdfcrystal field parametersg-factorsLiYF<sub>4</sub>:Ce<sup>3+</sup>
spellingShingle O.V. Solovyev
Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystal
Magnetic Resonance in Solids
crystal field parameters
g-factors
LiYF<sub>4</sub>:Ce<sup>3+</sup>
title Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystal
title_full Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystal
title_fullStr Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystal
title_full_unstemmed Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystal
title_short Crystal field parameters and g-factors of the ground Kramers doublet of Ce<sup>3+</sup> ion in LiYF<sub>4</sub> crystal
title_sort crystal field parameters and g factors of the ground kramers doublet of ce sup 3 sup ion in liyf sub 4 sub crystal
topic crystal field parameters
g-factors
LiYF<sub>4</sub>:Ce<sup>3+</sup>
url http://mrsej.kpfu.ru/contents/2015/MRSej_15103.pdf
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