Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide type
The tetrakis complex of neodymium(III), tetrakis{μ-N-[bis(pyrrolidin-1-yl)phosphoryl]acetamidato}bis(propan-2-ol)neodymiumsodium propan-2-ol monosolvate, [NaNd(C10H16Cl3N3O2)4(C3H8O)2]·C3H8O or NaNdPyr4(i-PrOH)2·i-PrOH, with the amide type CAPh ligand bis(N,N-tetramethylene)(trichloroacetyl)phosphor...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-12-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989023010071 |
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| author | Nataliia S. Kariaka Viktoriya V. Dyakonenko Kateryna O. Znovjyak Svitlana V. Shishkina Volodymyr M. Amirkhanov |
| author_facet | Nataliia S. Kariaka Viktoriya V. Dyakonenko Kateryna O. Znovjyak Svitlana V. Shishkina Volodymyr M. Amirkhanov |
| author_sort | Nataliia S. Kariaka |
| collection | DOAJ |
| description | The tetrakis complex of neodymium(III), tetrakis{μ-N-[bis(pyrrolidin-1-yl)phosphoryl]acetamidato}bis(propan-2-ol)neodymiumsodium propan-2-ol monosolvate, [NaNd(C10H16Cl3N3O2)4(C3H8O)2]·C3H8O or NaNdPyr4(i-PrOH)2·i-PrOH, with the amide type CAPh ligand bis(N,N-tetramethylene)(trichloroacetyl)phosphoric acid triamide (HPyr), has been synthesized, crystallized and characterized by X-ray diffraction. The complex does not have the tetrakis(CAPh)lanthanide anion, which is typical for ester-type CAPh-based coordination compounds. Instead, the NdO8 polyhedron is formed by one oxygen atom of a 2-propanol molecule and seven oxygen atoms of CAPh ligands in the title compound. Three CAPh ligands are coordinated in a bidentate chelating manner to the NdIII ion and simultaneously binding the sodium cation by μ2-bridging PO and CO groups while the fourth CAPh ligand is coordinated to the sodium cation in a bidentate chelating manner and, due to the μ2-bridging function of the PO group, also binds the neodymium ion. |
| first_indexed | 2024-03-09T02:45:41Z |
| format | Article |
| id | doaj.art-bbe21d37f24a42e7bb905e1351850e16 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-03-09T02:45:41Z |
| publishDate | 2023-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-bbe21d37f24a42e7bb905e1351850e162023-12-05T17:04:07ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902023-12-0179121218122210.1107/S2056989023010071mw2199Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide typeNataliia S. Kariaka0Viktoriya V. Dyakonenko1Kateryna O. Znovjyak2Svitlana V. Shishkina3Volodymyr M. Amirkhanov4Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska str. 64, 01601 Kyiv, UkraineSSI "Institute for Single Crystals", National Academy of Sciences of Ukraine, Nauky ave. 60, 61001 Kharkiv, UkraineDepartment of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska str. 64, 01601 Kyiv, UkraineSSI "Institute for Single Crystals", National Academy of Sciences of Ukraine, Nauky ave. 60, 61001 Kharkiv, UkraineDepartment of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska str. 64, 01601 Kyiv, UkraineThe tetrakis complex of neodymium(III), tetrakis{μ-N-[bis(pyrrolidin-1-yl)phosphoryl]acetamidato}bis(propan-2-ol)neodymiumsodium propan-2-ol monosolvate, [NaNd(C10H16Cl3N3O2)4(C3H8O)2]·C3H8O or NaNdPyr4(i-PrOH)2·i-PrOH, with the amide type CAPh ligand bis(N,N-tetramethylene)(trichloroacetyl)phosphoric acid triamide (HPyr), has been synthesized, crystallized and characterized by X-ray diffraction. The complex does not have the tetrakis(CAPh)lanthanide anion, which is typical for ester-type CAPh-based coordination compounds. Instead, the NdO8 polyhedron is formed by one oxygen atom of a 2-propanol molecule and seven oxygen atoms of CAPh ligands in the title compound. Three CAPh ligands are coordinated in a bidentate chelating manner to the NdIII ion and simultaneously binding the sodium cation by μ2-bridging PO and CO groups while the fourth CAPh ligand is coordinated to the sodium cation in a bidentate chelating manner and, due to the μ2-bridging function of the PO group, also binds the neodymium ion.http://scripts.iucr.org/cgi-bin/paper?S2056989023010071crystal structurecarbacylamidophosphateneodymiumtetrakis-complex |
| spellingShingle | Nataliia S. Kariaka Viktoriya V. Dyakonenko Kateryna O. Znovjyak Svitlana V. Shishkina Volodymyr M. Amirkhanov Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide type Acta Crystallographica Section E: Crystallographic Communications crystal structure carbacylamidophosphate neodymium tetrakis-complex |
| title | Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide type |
| title_full | Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide type |
| title_fullStr | Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide type |
| title_full_unstemmed | Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide type |
| title_short | Synthesis, crystal structure and Hirshfeld surface analysis of the tetrakis complex NaNdPyr4(i-PrOH)2·i-PrOH with a carbacylamidophosphate of the amide type |
| title_sort | synthesis crystal structure and hirshfeld surface analysis of the tetrakis complex nandpyr4 i proh 2·i proh with a carbacylamidophosphate of the amide type |
| topic | crystal structure carbacylamidophosphate neodymium tetrakis-complex |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989023010071 |
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