Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor Applications

This work reports an alternative atomic layer deposition (ALD) method to fabricate ZnO thin-film transistors (TFTs). The ZnO film is deposited with temperature naturally-cooling process from 200 to 100°C, called a “temperature gradient ZnO (TG-ZnO)”). After optimized...

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Main Authors: Bowen Che, Hao Zhang, Jun Yang, Jie Qi, Xingwei Ding, Jianhua Zhang
Format: Article
Language:English
Published: IEEE 2020-01-01
Series:IEEE Journal of the Electron Devices Society
Subjects:
Online Access:https://ieeexplore.ieee.org/document/9162063/
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author Bowen Che
Hao Zhang
Jun Yang
Jie Qi
Xingwei Ding
Jianhua Zhang
author_facet Bowen Che
Hao Zhang
Jun Yang
Jie Qi
Xingwei Ding
Jianhua Zhang
author_sort Bowen Che
collection DOAJ
description This work reports an alternative atomic layer deposition (ALD) method to fabricate ZnO thin-film transistors (TFTs). The ZnO film is deposited with temperature naturally-cooling process from 200 to 100&#x00B0;C, called a &#x201C;temperature gradient ZnO (TG-ZnO)&#x201D;). After optimized annealing treatment at 300&#x00B0;C, the TG-ZnO TFT shows an excellent performance compared to those fabricated with traditional constant temperature deposition, including a high saturation mobility <inline-formula> <tex-math notation="LaTeX">$\left(\mu_{\text {sat }}\right)$ </tex-math></inline-formula> of 11.8 cm<sup>2</sup>/Vs, which is 5 times higher than the ZnO TFT, a good on/off-state current ratio <inline-formula> <tex-math notation="LaTeX">$\left(I_{\mathrm{on}} / I_{\mathrm{off}}\right)$ </tex-math></inline-formula> of <inline-formula> <tex-math notation="LaTeX">$1.9 \times 10^{7}$ </tex-math></inline-formula>, a small subthreshold swing (<inline-formula> <tex-math notation="LaTeX">$SS$ </tex-math></inline-formula>) of 175 mV/decade and a threshold voltage <inline-formula> <tex-math notation="LaTeX">$\left(V_{\mathrm{th}}\right)$ </tex-math></inline-formula> of 1.1 V. Meanwhile, the TG-ZnO TFT has better crystallization than 100&#x00B0;C-ZnO and lower oxygen vacancies than 200&#x00B0;C-ZnO. These characters enable the TG-ZnO TFT not only to maintain a high mobility, but also to present a satisfactory <inline-formula> <tex-math notation="LaTeX">$I_{\mathrm{on}} / I_{\mathrm{off}}$ </tex-math></inline-formula> ratio. This promising deposition technique provides a new idea for fabricating TFTs with high mobility.
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spelling doaj.art-bc1bc0b4c6fd4ffaa6028db1de49fac22022-12-21T22:07:35ZengIEEEIEEE Journal of the Electron Devices Society2168-67342020-01-01888588910.1109/JEDS.2020.30150309162063Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor ApplicationsBowen Che0https://orcid.org/0000-0002-2024-1878Hao Zhang1Jun Yang2Jie Qi3Xingwei Ding4https://orcid.org/0000-0002-9002-5185Jianhua Zhang5Key Laboratory of Advanced Display and System Application, Ministry of Education, Shanghai University, Shanghai, ChinaCollege of Electronics and Information Science, Organic Optoelectronics Engineering Research Center of Fujian’s Universities, Fujian Jiangxia University, Fujian, ChinaKey Laboratory of Advanced Display and System Application, Ministry of Education, Shanghai University, Shanghai, ChinaResearch and Development Department, Air Liquide Innovation Campus Shanghai, Shanghai, ChinaKey Laboratory of Advanced Display and System Application, Ministry of Education, Shanghai University, Shanghai, ChinaKey Laboratory of Advanced Display and System Application, Ministry of Education, Shanghai University, Shanghai, ChinaThis work reports an alternative atomic layer deposition (ALD) method to fabricate ZnO thin-film transistors (TFTs). The ZnO film is deposited with temperature naturally-cooling process from 200 to 100&#x00B0;C, called a &#x201C;temperature gradient ZnO (TG-ZnO)&#x201D;). After optimized annealing treatment at 300&#x00B0;C, the TG-ZnO TFT shows an excellent performance compared to those fabricated with traditional constant temperature deposition, including a high saturation mobility <inline-formula> <tex-math notation="LaTeX">$\left(\mu_{\text {sat }}\right)$ </tex-math></inline-formula> of 11.8 cm<sup>2</sup>/Vs, which is 5 times higher than the ZnO TFT, a good on/off-state current ratio <inline-formula> <tex-math notation="LaTeX">$\left(I_{\mathrm{on}} / I_{\mathrm{off}}\right)$ </tex-math></inline-formula> of <inline-formula> <tex-math notation="LaTeX">$1.9 \times 10^{7}$ </tex-math></inline-formula>, a small subthreshold swing (<inline-formula> <tex-math notation="LaTeX">$SS$ </tex-math></inline-formula>) of 175 mV/decade and a threshold voltage <inline-formula> <tex-math notation="LaTeX">$\left(V_{\mathrm{th}}\right)$ </tex-math></inline-formula> of 1.1 V. Meanwhile, the TG-ZnO TFT has better crystallization than 100&#x00B0;C-ZnO and lower oxygen vacancies than 200&#x00B0;C-ZnO. These characters enable the TG-ZnO TFT not only to maintain a high mobility, but also to present a satisfactory <inline-formula> <tex-math notation="LaTeX">$I_{\mathrm{on}} / I_{\mathrm{off}}$ </tex-math></inline-formula> ratio. This promising deposition technique provides a new idea for fabricating TFTs with high mobility.https://ieeexplore.ieee.org/document/9162063/Thin-film transistorstemperature gradient ZnOatomic layer depositionoxygen vacancy
spellingShingle Bowen Che
Hao Zhang
Jun Yang
Jie Qi
Xingwei Ding
Jianhua Zhang
Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor Applications
IEEE Journal of the Electron Devices Society
Thin-film transistors
temperature gradient ZnO
atomic layer deposition
oxygen vacancy
title Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor Applications
title_full Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor Applications
title_fullStr Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor Applications
title_full_unstemmed Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor Applications
title_short Temperature Gradient ZnO Deposited via ALD for High-Performance Transistor Applications
title_sort temperature gradient zno deposited via ald for high performance transistor applications
topic Thin-film transistors
temperature gradient ZnO
atomic layer deposition
oxygen vacancy
url https://ieeexplore.ieee.org/document/9162063/
work_keys_str_mv AT bowenche temperaturegradientznodepositedviaaldforhighperformancetransistorapplications
AT haozhang temperaturegradientznodepositedviaaldforhighperformancetransistorapplications
AT junyang temperaturegradientznodepositedviaaldforhighperformancetransistorapplications
AT jieqi temperaturegradientznodepositedviaaldforhighperformancetransistorapplications
AT xingweiding temperaturegradientznodepositedviaaldforhighperformancetransistorapplications
AT jianhuazhang temperaturegradientznodepositedviaaldforhighperformancetransistorapplications