Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a review

A considerable amount of secondary aluminum dross is generated in the aluminum refining process. Secondary aluminum dross (SAD) is hazardous waste because of its constituent pollutants, such as AlN, fluoride, chloride, and heavy metal pollutants. SAD treatment can be categorized into thermal and wet...

Full description

Bibliographic Details
Main Authors: Xinghan Zhu, Jinzhong Yang, Yufei Yang, Qifei Huang, Tao Liu
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S223878542201496X
_version_ 1811292748313001984
author Xinghan Zhu
Jinzhong Yang
Yufei Yang
Qifei Huang
Tao Liu
author_facet Xinghan Zhu
Jinzhong Yang
Yufei Yang
Qifei Huang
Tao Liu
author_sort Xinghan Zhu
collection DOAJ
description A considerable amount of secondary aluminum dross is generated in the aluminum refining process. Secondary aluminum dross (SAD) is hazardous waste because of its constituent pollutants, such as AlN, fluoride, chloride, and heavy metal pollutants. SAD treatment can be categorized into thermal and wet methods. The thermal process has attracted considerable research attention because of its simplicity and ability to prepare Al–Mg spinels, refractory materials, and ceramics and recover alumina during the treatment. However, at this stage, SAD pyrolysis processes are typically focused on the removal of single pollutants. Limited studies have explored the simultaneous removal of various pollutants and their interactions. This study focused on the pyroprocess in the SAD treatment process and investigated the SAD mechanism in the preparation of Al–Mg spinel, refractories, ceramics, and recycled alumina. Furthermore, the conversion of AlN, fluoride, chloride salts, and heavy metals, which are the main pollutants generated in the thermal reaction of SAD, and their control mechanisms were analyzed. The synergistic mechanism of SAD denitrification∖chlorine salt and fluoride fixation∖heavy metal was studied through the reaction mechanism of similar component minerals in the pyroprocess for improving the high-value utilization of SAD and scientific prevention and control of secondary pollution. Finally, the feasibility of preparing ceramic pellets from aluminum dross (AD) was evaluated. The results of the study can provide crucial development directions for SAD utilization.
first_indexed 2024-04-13T04:50:02Z
format Article
id doaj.art-bc3de2264c604d34b7e37a9b4ad99f51
institution Directory Open Access Journal
issn 2238-7854
language English
last_indexed 2024-04-13T04:50:02Z
publishDate 2022-11-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj.art-bc3de2264c604d34b7e37a9b4ad99f512022-12-22T03:01:42ZengElsevierJournal of Materials Research and Technology2238-78542022-11-012111961211Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a reviewXinghan Zhu0Jinzhong Yang1Yufei Yang2Qifei Huang3Tao Liu4State Key Laboratory of Environmental Benchmarks and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, ChinaState Key Laboratory of Environmental Benchmarks and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; Corresponding author.State Key Laboratory of Environmental Benchmarks and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing 100012, ChinaState Key Laboratory of Environmental Benchmarks and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China; State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences, Beijing 100012, ChinaCollege of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China; Corresponding author.A considerable amount of secondary aluminum dross is generated in the aluminum refining process. Secondary aluminum dross (SAD) is hazardous waste because of its constituent pollutants, such as AlN, fluoride, chloride, and heavy metal pollutants. SAD treatment can be categorized into thermal and wet methods. The thermal process has attracted considerable research attention because of its simplicity and ability to prepare Al–Mg spinels, refractory materials, and ceramics and recover alumina during the treatment. However, at this stage, SAD pyrolysis processes are typically focused on the removal of single pollutants. Limited studies have explored the simultaneous removal of various pollutants and their interactions. This study focused on the pyroprocess in the SAD treatment process and investigated the SAD mechanism in the preparation of Al–Mg spinel, refractories, ceramics, and recycled alumina. Furthermore, the conversion of AlN, fluoride, chloride salts, and heavy metals, which are the main pollutants generated in the thermal reaction of SAD, and their control mechanisms were analyzed. The synergistic mechanism of SAD denitrification∖chlorine salt and fluoride fixation∖heavy metal was studied through the reaction mechanism of similar component minerals in the pyroprocess for improving the high-value utilization of SAD and scientific prevention and control of secondary pollution. Finally, the feasibility of preparing ceramic pellets from aluminum dross (AD) was evaluated. The results of the study can provide crucial development directions for SAD utilization.http://www.sciencedirect.com/science/article/pii/S223878542201496XSecondary aluminum drossde-nitrogenization and fluoride fixationSynergismPollutant treatmentCeramic pellets
spellingShingle Xinghan Zhu
Jinzhong Yang
Yufei Yang
Qifei Huang
Tao Liu
Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a review
Journal of Materials Research and Technology
Secondary aluminum dross
de-nitrogenization and fluoride fixation
Synergism
Pollutant treatment
Ceramic pellets
title Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a review
title_full Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a review
title_fullStr Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a review
title_full_unstemmed Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a review
title_short Pyrometallurgical process and multipollutant co-conversion for secondary aluminum dross: a review
title_sort pyrometallurgical process and multipollutant co conversion for secondary aluminum dross a review
topic Secondary aluminum dross
de-nitrogenization and fluoride fixation
Synergism
Pollutant treatment
Ceramic pellets
url http://www.sciencedirect.com/science/article/pii/S223878542201496X
work_keys_str_mv AT xinghanzhu pyrometallurgicalprocessandmultipollutantcoconversionforsecondaryaluminumdrossareview
AT jinzhongyang pyrometallurgicalprocessandmultipollutantcoconversionforsecondaryaluminumdrossareview
AT yufeiyang pyrometallurgicalprocessandmultipollutantcoconversionforsecondaryaluminumdrossareview
AT qifeihuang pyrometallurgicalprocessandmultipollutantcoconversionforsecondaryaluminumdrossareview
AT taoliu pyrometallurgicalprocessandmultipollutantcoconversionforsecondaryaluminumdrossareview