Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water

Methoxy polyethylene glycol modified magnetite nanoparticles (PEGMNs) were synthesized and characterized by scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and X-ray diffraction (XRD). The adsorption of diazinon onto PEGMNs was investigated by UV-Vis spectrophotometry at 236...

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Main Authors: Mahboubeh Saeidi, Atena Naeimi, Marzie Komeili
Format: Article
Language:English
Published: Iranian Research Organization for Science and Technology (IROST) 2016-12-01
Series:Advances in Environmental Technology
Subjects:
Online Access:http://aet.irost.ir/article_350_b3042b07c41d968969bb5ec718788fa7.pdf
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author Mahboubeh Saeidi
Atena Naeimi
Marzie Komeili
author_facet Mahboubeh Saeidi
Atena Naeimi
Marzie Komeili
author_sort Mahboubeh Saeidi
collection DOAJ
description Methoxy polyethylene glycol modified magnetite nanoparticles (PEGMNs) were synthesized and characterized by scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and X-ray diffraction (XRD). The adsorption of diazinon onto PEGMNs was investigated by UV-Vis spectrophotometry at 236 nm, through batch experiments. The effects of adsorbent dosage, solution pH, contact time, solution temperature and water impurities on the adsorption of diazinon onto PEGMNs were investigated. The process of adsorption was increased rapidly in the first contact period of 10 min. The adsorption at equilibrium (qe) was found to increase with increasing pH. The results of diazinon removal at various PEGMNs dosages demonstrated that the optimum dose of PEGMNs was 1mg. The amount of adsorption of diazinon at equilibrium increased with an increasing temperature from 15°C to 45°C that indicateds an endothermic process. Therefore, PEGMNs were used as an efficient absorbent for the removal of diazinon.
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spelling doaj.art-bc46291207034901a6ab45eda6d49b3f2022-12-21T20:04:32ZengIranian Research Organization for Science and Technology (IROST)Advances in Environmental Technology2476-66742476-47792016-12-0121253110.22104/aet.2016.350350Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from waterMahboubeh Saeidi0Atena Naeimi1Marzie Komeili2Department of Chemistry, Faculty of Science, Vali-e- Asr University of Rafsanjan, IranFaculty of Science, Department of Chemistry, University of Jiroft, Jiroft, IranDepartment of Chemistry, Faculty of Science, Vali-e- Asr University of Rafsanjan, IranMethoxy polyethylene glycol modified magnetite nanoparticles (PEGMNs) were synthesized and characterized by scanning electron microscopy (SEM), vibrating sample magnetometer (VSM), and X-ray diffraction (XRD). The adsorption of diazinon onto PEGMNs was investigated by UV-Vis spectrophotometry at 236 nm, through batch experiments. The effects of adsorbent dosage, solution pH, contact time, solution temperature and water impurities on the adsorption of diazinon onto PEGMNs were investigated. The process of adsorption was increased rapidly in the first contact period of 10 min. The adsorption at equilibrium (qe) was found to increase with increasing pH. The results of diazinon removal at various PEGMNs dosages demonstrated that the optimum dose of PEGMNs was 1mg. The amount of adsorption of diazinon at equilibrium increased with an increasing temperature from 15°C to 45°C that indicateds an endothermic process. Therefore, PEGMNs were used as an efficient absorbent for the removal of diazinon.http://aet.irost.ir/article_350_b3042b07c41d968969bb5ec718788fa7.pdfadsorptionspectrophotometrypesticidesfe3o4
spellingShingle Mahboubeh Saeidi
Atena Naeimi
Marzie Komeili
Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water
Advances in Environmental Technology
adsorption
spectrophotometry
pesticides
fe3o4
title Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water
title_full Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water
title_fullStr Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water
title_full_unstemmed Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water
title_short Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water
title_sort magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water
topic adsorption
spectrophotometry
pesticides
fe3o4
url http://aet.irost.ir/article_350_b3042b07c41d968969bb5ec718788fa7.pdf
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AT atenanaeimi magnetitenanoparticlescoatedwithmethoxypolyethyleneglycolasanefficientadsorbentofdiazinonpesticidefromwater
AT marziekomeili magnetitenanoparticlescoatedwithmethoxypolyethyleneglycolasanefficientadsorbentofdiazinonpesticidefromwater