Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXene
Metronidazole is a widely used antibiotic with powerful antimicrobial properties, but its presence in water can be detrimental to aquatic life and human health. To address this issue, we developed a novel composite material, zero-valent iron nanoparticles on alkalized Ti3C2Tx nanoflakes (NZVI/Ti3C2T...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-10-01
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| Series: | Alexandria Engineering Journal |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S1110016823007408 |
| _version_ | 1827798985035743232 |
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| author | Chen Chen Wan Luo Jinming Xu Dongchun Niu |
| author_facet | Chen Chen Wan Luo Jinming Xu Dongchun Niu |
| author_sort | Chen Chen |
| collection | DOAJ |
| description | Metronidazole is a widely used antibiotic with powerful antimicrobial properties, but its presence in water can be detrimental to aquatic life and human health. To address this issue, we developed a novel composite material, zero-valent iron nanoparticles on alkalized Ti3C2Tx nanoflakes (NZVI/Ti3C2Tx), using an in-situ growth technique, aiming to efficiently adsorb and degrade metronidazole from aqueous solutions. The incorporation of Ti3C2Tx in NZVI/Ti3C2Tx resulted in enhanced dispersion, stability, and reactivity of NZVI. Our study demonstrated that NZVI/Ti3C2Tx exhibited the highest metronidazole removal efficiency (95.80%) within just 10 min of reaction time, outperforming NZVI and Ti3C2Tx alone. To optimize the removal process, we investigated the influence of various parameters on the degradation of metronidazole by NZVI/Ti3C2Tx, including the NZVI/Ti3C2Tx ratio, initial metronidazole concentration, pH, and reaction temperature. The highest removal rate was achieved with an NZVI/Ti3C2Tx ratio of 2:1 after 90 min of reaction time. As the initial concentration and pH of metronidazole increased, the removal efficiency decreased, while higher reaction temperatures improved the removal efficiency. Kinetic studies revealed that the degradation of metronidazole by NZVI/Ti3C2Tx followed a modified second-order parameter pseudo-first-order kinetic model, highlighting the effective reduction reaction. The unique properties of MXene nanosheets and NZVI synergistically contributed to the enhanced removal performance, with NZVI/Ti3C2Tx acting as an efficient adsorbent and reducing agent. Uur findings demonstrate the potential of the NZVI/Ti3C2Tx nanocomposite as an efficient and eco-friendly approach for the removal of metronidazole from agricultural wastewater. The combination of NZVI and Ti3C2Tx offers enhanced removal efficiency and stability, making it a promising material for water purification and environmental applications. |
| first_indexed | 2024-03-11T19:43:47Z |
| format | Article |
| id | doaj.art-bc4f0dc6a1904b25a35d742f2a8b0650 |
| institution | Directory Open Access Journal |
| issn | 1110-0168 |
| language | English |
| last_indexed | 2024-03-11T19:43:47Z |
| publishDate | 2023-10-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Alexandria Engineering Journal |
| spelling | doaj.art-bc4f0dc6a1904b25a35d742f2a8b06502023-10-06T04:44:01ZengElsevierAlexandria Engineering Journal1110-01682023-10-01804147Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXeneChen Chen0Wan Luo1Jinming Xu2Dongchun Niu3College of Hydraulic Engineering, Jiangsu Vocational Institute of Architectural Technology, Xuzhou 221000, China; College of Water Resources and Hydropower Engineering, Yangzhou University, Yangzhou 225009, China; Corresponding authors at: College of Hydraulic Engineering, Jiangsu Vocational Institute of Architectural Technology, Xuzhou 221000, China (C. Chen).College of Water Resources and Hydropower Engineering, Yangzhou University, Yangzhou 225009, China; Corresponding authors at: College of Hydraulic Engineering, Jiangsu Vocational Institute of Architectural Technology, Xuzhou 221000, China (C. Chen).College of Water Resources and Hydropower Engineering, Yangzhou University, Yangzhou 225009, China; Water Supply and Drainage Management Centre, Xuzhou 221000, ChinaWater Conservancy Project Construction Management Center, Xuzhou 221000, ChinaMetronidazole is a widely used antibiotic with powerful antimicrobial properties, but its presence in water can be detrimental to aquatic life and human health. To address this issue, we developed a novel composite material, zero-valent iron nanoparticles on alkalized Ti3C2Tx nanoflakes (NZVI/Ti3C2Tx), using an in-situ growth technique, aiming to efficiently adsorb and degrade metronidazole from aqueous solutions. The incorporation of Ti3C2Tx in NZVI/Ti3C2Tx resulted in enhanced dispersion, stability, and reactivity of NZVI. Our study demonstrated that NZVI/Ti3C2Tx exhibited the highest metronidazole removal efficiency (95.80%) within just 10 min of reaction time, outperforming NZVI and Ti3C2Tx alone. To optimize the removal process, we investigated the influence of various parameters on the degradation of metronidazole by NZVI/Ti3C2Tx, including the NZVI/Ti3C2Tx ratio, initial metronidazole concentration, pH, and reaction temperature. The highest removal rate was achieved with an NZVI/Ti3C2Tx ratio of 2:1 after 90 min of reaction time. As the initial concentration and pH of metronidazole increased, the removal efficiency decreased, while higher reaction temperatures improved the removal efficiency. Kinetic studies revealed that the degradation of metronidazole by NZVI/Ti3C2Tx followed a modified second-order parameter pseudo-first-order kinetic model, highlighting the effective reduction reaction. The unique properties of MXene nanosheets and NZVI synergistically contributed to the enhanced removal performance, with NZVI/Ti3C2Tx acting as an efficient adsorbent and reducing agent. Uur findings demonstrate the potential of the NZVI/Ti3C2Tx nanocomposite as an efficient and eco-friendly approach for the removal of metronidazole from agricultural wastewater. The combination of NZVI and Ti3C2Tx offers enhanced removal efficiency and stability, making it a promising material for water purification and environmental applications.http://www.sciencedirect.com/science/article/pii/S1110016823007408MXene nanosheetsZero-valent iron nanoparticlesMetronidazoleReductionAdsorption |
| spellingShingle | Chen Chen Wan Luo Jinming Xu Dongchun Niu Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXene Alexandria Engineering Journal MXene nanosheets Zero-valent iron nanoparticles Metronidazole Reduction Adsorption |
| title | Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXene |
| title_full | Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXene |
| title_fullStr | Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXene |
| title_full_unstemmed | Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXene |
| title_short | Investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nZVI on MXene |
| title_sort | investigation of the adsorption and degradation of metronidazole residues in agricultural wastewater by nanocomposite based on nzvi on mxene |
| topic | MXene nanosheets Zero-valent iron nanoparticles Metronidazole Reduction Adsorption |
| url | http://www.sciencedirect.com/science/article/pii/S1110016823007408 |
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