Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluids

Adsorbent is an important waste water-based drilling fluid treatment agent, which can adsorb and settle heavy metal ions, high polymer organics, and other soluble harmful substances in the waste drilling fluid. Traditional adsorbents such as polyaluminum chloride and polyacrylamide will produce othe...

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Main Authors: Guo Yong, Nie Minghu, Wang Yingjie, Zhong Zhen, Liu Yunfeng
Format: Article
Language:English
Published: De Gruyter 2022-03-01
Series:Reviews on Advanced Materials Science
Subjects:
Online Access:https://doi.org/10.1515/rams-2022-0022
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author Guo Yong
Nie Minghu
Wang Yingjie
Zhong Zhen
Liu Yunfeng
author_facet Guo Yong
Nie Minghu
Wang Yingjie
Zhong Zhen
Liu Yunfeng
author_sort Guo Yong
collection DOAJ
description Adsorbent is an important waste water-based drilling fluid treatment agent, which can adsorb and settle heavy metal ions, high polymer organics, and other soluble harmful substances in the waste drilling fluid. Traditional adsorbents such as polyaluminum chloride and polyacrylamide will produce other metal ions or toxic monomers after hydrolysis, which cannot fully meet the requirements of safety and environmental protection. Therefore, a new environmentally friendly waste water-based drilling fluid adsorbent, named RH-β-CD, was prepared by the Wilson etherification reaction, which was initiated by epichlorohydrin and ceric ammonium nitrate, and successfully grafted rhamnolipid and amine strong adsorption groups onto β-cyclodextrin. The adsorption effect and environmental protection performance of RH-β-CD on the organic matter and chromium ion in waste sulfonated water-based drilling fluid were evaluated and compared with commonly used adsorbents such as activated carbon, PAM, and polyaluminum chloride. The results show that RH-β-CD can effectively adsorb the organic matter in the filtrate of waste water-based drilling fluids, reduce its chemical oxygen consumption, and reduce the concentration of heavy metal ions in the filtrate. The effect is better than PAM, activated carbon, and polyaluminum chloride, with the BOD5/CODcr >20% and EC50 >1,000,000 mg·L−1, which is environmentally friendly.
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spelling doaj.art-bc6422cdc15342e6bd834188248528832022-12-22T03:24:46ZengDe GruyterReviews on Advanced Materials Science1605-81272022-03-0161113814510.1515/rams-2022-0022Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluidsGuo Yong0Nie Minghu1Wang Yingjie2Zhong Zhen3Liu Yunfeng4Engineering Technology Research Institute, PetroChina Xinjiang Oilfield Company, Karamay, Xinjiang 834000, ChinaEngineering Technology Research Institute, PetroChina Xinjiang Oilfield Company, Karamay, Xinjiang 834000, ChinaEngineering Technology Research Institute, PetroChina Xinjiang Oilfield Company, Karamay, Xinjiang 834000, ChinaEngineering Technology Research Institute, PetroChina Xinjiang Oilfield Company, Karamay, Xinjiang 834000, ChinaResearch Institute of Natural Gas Technology, Southwest Oil and Gas Field Company of PetroChina, Chengdu 610213, ChinaAdsorbent is an important waste water-based drilling fluid treatment agent, which can adsorb and settle heavy metal ions, high polymer organics, and other soluble harmful substances in the waste drilling fluid. Traditional adsorbents such as polyaluminum chloride and polyacrylamide will produce other metal ions or toxic monomers after hydrolysis, which cannot fully meet the requirements of safety and environmental protection. Therefore, a new environmentally friendly waste water-based drilling fluid adsorbent, named RH-β-CD, was prepared by the Wilson etherification reaction, which was initiated by epichlorohydrin and ceric ammonium nitrate, and successfully grafted rhamnolipid and amine strong adsorption groups onto β-cyclodextrin. The adsorption effect and environmental protection performance of RH-β-CD on the organic matter and chromium ion in waste sulfonated water-based drilling fluid were evaluated and compared with commonly used adsorbents such as activated carbon, PAM, and polyaluminum chloride. The results show that RH-β-CD can effectively adsorb the organic matter in the filtrate of waste water-based drilling fluids, reduce its chemical oxygen consumption, and reduce the concentration of heavy metal ions in the filtrate. The effect is better than PAM, activated carbon, and polyaluminum chloride, with the BOD5/CODcr >20% and EC50 >1,000,000 mg·L−1, which is environmentally friendly.https://doi.org/10.1515/rams-2022-0022waste water-based drilling fluidscyclodextrinadsorbentheavy metal pollutionenvironmentally friendly
spellingShingle Guo Yong
Nie Minghu
Wang Yingjie
Zhong Zhen
Liu Yunfeng
Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluids
Reviews on Advanced Materials Science
waste water-based drilling fluids
cyclodextrin
adsorbent
heavy metal pollution
environmentally friendly
title Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluids
title_full Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluids
title_fullStr Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluids
title_full_unstemmed Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluids
title_short Development and performance evaluation of a novel environmentally friendly adsorbent for waste water-based drilling fluids
title_sort development and performance evaluation of a novel environmentally friendly adsorbent for waste water based drilling fluids
topic waste water-based drilling fluids
cyclodextrin
adsorbent
heavy metal pollution
environmentally friendly
url https://doi.org/10.1515/rams-2022-0022
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AT wangyingjie developmentandperformanceevaluationofanovelenvironmentallyfriendlyadsorbentforwastewaterbaseddrillingfluids
AT zhongzhen developmentandperformanceevaluationofanovelenvironmentallyfriendlyadsorbentforwastewaterbaseddrillingfluids
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