Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)]

The asymmetric unit of the title compound, [Nd(C9H3O6)(C2H6OS)2]n, contains one Nd3+ ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd3+ ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and...

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Bibliographic Details
Main Authors: Zhongyue Li, Kun Liu
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811049622
Description
Summary:The asymmetric unit of the title compound, [Nd(C9H3O6)(C2H6OS)2]n, contains one Nd3+ ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd3+ ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and two O atoms from two dimethyl sulfoxide molecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxylate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxylate groups and dimethyl sulfoxide molecules, forming a three-dimensional polymeric rare earth metal-organic framework structure.
ISSN:1600-5368