Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)]
The asymmetric unit of the title compound, [Nd(C9H3O6)(C2H6OS)2]n, contains one Nd3+ ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd3+ ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811049622 |
| _version_ | 1819121770341335040 |
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| author | Zhongyue Li Kun Liu |
| author_facet | Zhongyue Li Kun Liu |
| author_sort | Zhongyue Li |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Nd(C9H3O6)(C2H6OS)2]n, contains one Nd3+ ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd3+ ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and two O atoms from two dimethyl sulfoxide molecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxylate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxylate groups and dimethyl sulfoxide molecules, forming a three-dimensional polymeric rare earth metal-organic framework structure. |
| first_indexed | 2024-12-22T06:41:50Z |
| format | Article |
| id | doaj.art-bc789de3a612436fb4f08c830cec787f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T06:41:50Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-bc789de3a612436fb4f08c830cec787f2022-12-21T18:35:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1833m183310.1107/S1600536811049622Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)]Zhongyue LiKun LiuThe asymmetric unit of the title compound, [Nd(C9H3O6)(C2H6OS)2]n, contains one Nd3+ ion, one benzene-1,3,5-tricarboxylic ligand and two coordinating dimethyl sulfoxide molecules. The Nd3+ ion is coordinated by six O atoms from four carboxylate groups of the benzene-1,3,5-tricarboxylate ligands and two O atoms from two dimethyl sulfoxide molecules. The metal-organic cluster formed upon symmetry expansion of the asymmetric unit consists of two metal atoms and four benzene-1,3,5-tricarboxylate groups, creating a paddle-wheel-type building block arrangement. The remaining coordination sites are occupied by additional benzene-1,3,5-tricarboxylate groups and dimethyl sulfoxide molecules, forming a three-dimensional polymeric rare earth metal-organic framework structure.http://scripts.iucr.org/cgi-bin/paper?S1600536811049622 |
| spellingShingle | Zhongyue Li Kun Liu Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] Acta Crystallographica Section E |
| title | Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
| title_full | Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
| title_fullStr | Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
| title_full_unstemmed | Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
| title_short | Poly[(μ4-benzene-1,3,5-tricarboxylato)bis(dimethyl sulfoxide-κO)neodymium(III)] |
| title_sort | poly amp 956 4 benzene 1 3 5 tricarboxylato bis dimethyl sulfoxide amp 954 o neodymium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811049622 |
| work_keys_str_mv | AT zhongyueli polyamp9564benzene135tricarboxylatobisdimethylsulfoxideamp954oneodymiumiii AT kunliu polyamp9564benzene135tricarboxylatobisdimethylsulfoxideamp954oneodymiumiii |