The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell

This paper shows use of starch-based carbon (CSC) and graphene as the anode electrode for lithium-ion cell. To describe electrochemical stability of the half-cell system and kinetic parameters of charging process in different temperatures, electrochemical impedance spectroscopy (EIS) measurement was...

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Main Authors: Beata Kurc, Marita Pigłowska, Łukasz Rymaniak
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/23/7/861
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author Beata Kurc
Marita Pigłowska
Łukasz Rymaniak
author_facet Beata Kurc
Marita Pigłowska
Łukasz Rymaniak
author_sort Beata Kurc
collection DOAJ
description This paper shows use of starch-based carbon (CSC) and graphene as the anode electrode for lithium-ion cell. To describe electrochemical stability of the half-cell system and kinetic parameters of charging process in different temperatures, electrochemical impedance spectroscopy (EIS) measurement was adopted. It has been shown that smaller resistances are observed for CSC. Additionally, Bode plots show high electrochemical stability at higher temperatures. The activation energy for the SEI (solid–electrolyte interface) layer, charge transfer, and electrolyte were in the ranges of 24.06–25.33, 68.18–118.55, and 13.84–15.22 kJ mol<sup>−1</sup>, respectively. Moreover, the activation energy of most processes is smaller for CSC, which means that this electrode could serve as an eco-friendly biodegradable lithium-ion cell element.
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spelling doaj.art-bc8ada4771174aa392086d37e87df3e12023-11-22T03:44:56ZengMDPI AGEntropy1099-43002021-07-0123786110.3390/e23070861The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion CellBeata Kurc0Marita Pigłowska1Łukasz Rymaniak2Institute of Chemistry and Electrochemistry, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, PL-60965 Poznan, PolandFaculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, PL-60965 Poznan, PolandInstitute of Combustion Engines and Powertrains, Faculty of Civil and Transport Engineering, Poznan University of Technology, Piotrowo 3, PL-60965 Poznan, PolandThis paper shows use of starch-based carbon (CSC) and graphene as the anode electrode for lithium-ion cell. To describe electrochemical stability of the half-cell system and kinetic parameters of charging process in different temperatures, electrochemical impedance spectroscopy (EIS) measurement was adopted. It has been shown that smaller resistances are observed for CSC. Additionally, Bode plots show high electrochemical stability at higher temperatures. The activation energy for the SEI (solid–electrolyte interface) layer, charge transfer, and electrolyte were in the ranges of 24.06–25.33, 68.18–118.55, and 13.84–15.22 kJ mol<sup>−1</sup>, respectively. Moreover, the activation energy of most processes is smaller for CSC, which means that this electrode could serve as an eco-friendly biodegradable lithium-ion cell element.https://www.mdpi.com/1099-4300/23/7/861starchcarbonEISBode plotsSEI
spellingShingle Beata Kurc
Marita Pigłowska
Łukasz Rymaniak
The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell
Entropy
starch
carbon
EIS
Bode plots
SEI
title The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell
title_full The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell
title_fullStr The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell
title_full_unstemmed The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell
title_short The Electrochemical Stability of Starch Carbon as an Important Property in the Construction of a Lithium-Ion Cell
title_sort electrochemical stability of starch carbon as an important property in the construction of a lithium ion cell
topic starch
carbon
EIS
Bode plots
SEI
url https://www.mdpi.com/1099-4300/23/7/861
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